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@ARTICLE{Boeddinghaus:151898,
      author       = {Boeddinghaus, M. Bele and Klein, Wilhelm and Wahl, Bernhard
                      and Jakes, Peter and Eichel, Rüdiger-A. and Fässler,
                      Thomas F.},
      title        = {{C} 60 3- versus {C} 60 4- /{C} 60 2- - {S}ynthesis and
                      {C}haracterization of {F}ive {S}alts {C}ontaining {D}iscrete
                      {F}ullerene {A}nions},
      journal      = {Zeitschrift für anorganische und allgemeine Chemie},
      volume       = {640},
      number       = {(5)},
      issn         = {0044-2313},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2014-01748},
      pages        = {701-712},
      year         = {2014},
      note         = {Bitte POF III ergänzen. Vielen Dank.Early View, Keywords:
                      Crystal structure determination; Fullerenes; Jahn-Teller
                      effect; Magnetic properties; Polyanions},
      abstract     = {Five new compounds, [Rb(18crown-6)]3[C60] (1),
                      [Rb(18crown-6)]6[C60]2(C3H7NO)2(C4H8O)2 (2),
                      [Rb(benzo18crown-6)]6[C60]2(C2H8N2)5 (3),
                      [Cs(benzo18crown-6)]3C60(C2H8N2)2 (4), and
                      [Cs3(benzo18crown-6)5]C60(C2H8N2)(4.5+x) (5) were
                      synthesized and characterized by single-crystal X-ray
                      structure determination. All compounds contain discrete C60
                      anions, which are ordered in 1, 2, and 4, where direct
                      cation-anion contacts occur. The unit cells of 1 and 2
                      contain two independent fullerides, which coordinate to the
                      rubidium atoms either of two or of four [Rb(18crown-6)]
                      units. Owing to the presence of differently coordinated
                      fullerene units in compounds 1 and 2, a possible
                      disproportionation of C603– into C602– and C604–
                      anions is discussed. In 3 and 4 the C60 anions are
                      coordinated by three Rb and Cs atoms, respectively. In all
                      compounds the average charge of the anion is –3. Magnetic
                      data reveal a doublet spin state for 3. The EPR spectra are
                      discussed for compounds 3 and 5. The role of a dynamic
                      Jahn-Teller distortion is discussed, and we report the first
                      IR spectroscopic data of fullerene trianions, which have
                      been obtained in solution.},
      cin          = {IEK-9},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {123 - Fuel Cells (POF2-123) / 152 - Renewable Energies
                      (POF2-152)},
      pid          = {G:(DE-HGF)POF2-123 / G:(DE-HGF)POF2-152},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000333697200004},
      doi          = {10.1002/zaac.201300607},
      url          = {https://juser.fz-juelich.de/record/151898},
}