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| Home > Publications database > C 60 3- versus C 60 4- /C 60 2- - Synthesis and Characterization of Five Salts Containing Discrete Fullerene Anions > print |
| Home > Publications database > C 60 3- versus C 60 4- /C 60 2- - Synthesis and Characterization of Five Salts Containing Discrete Fullerene Anions > print |
| 001 | 151898 | ||
| 005 | 20240712112817.0 | ||
| 024 | 7 | _ | |a 10.1002/zaac.201300607 |2 doi |
| 024 | 7 | _ | |a 0044-2313 |2 ISSN |
| 024 | 7 | _ | |a 1521-3749 |2 ISSN |
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| 037 | _ | _ | |a FZJ-2014-01748 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Boeddinghaus, M. Bele |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a C 60 3- versus C 60 4- /C 60 2- - Synthesis and Characterization of Five Salts Containing Discrete Fullerene Anions |
| 260 | _ | _ | |a Weinheim |c 2014 |b Wiley-VCH |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1403098925_30221 |2 PUB:(DE-HGF) |
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| 336 | 7 | _ | |a article |2 DRIVER |
| 500 | _ | _ | |a Bitte POF III ergänzen. Vielen Dank.Early View, Keywords: Crystal structure determination; Fullerenes; Jahn-Teller effect; Magnetic properties; Polyanions |
| 520 | _ | _ | |a Five new compounds, [Rb(18crown-6)]3[C60] (1), [Rb(18crown-6)]6[C60]2(C3H7NO)2(C4H8O)2 (2), [Rb(benzo18crown-6)]6[C60]2(C2H8N2)5 (3), [Cs(benzo18crown-6)]3C60(C2H8N2)2 (4), and [Cs3(benzo18crown-6)5]C60(C2H8N2)(4.5+x) (5) were synthesized and characterized by single-crystal X-ray structure determination. All compounds contain discrete C60 anions, which are ordered in 1, 2, and 4, where direct cation-anion contacts occur. The unit cells of 1 and 2 contain two independent fullerides, which coordinate to the rubidium atoms either of two or of four [Rb(18crown-6)] units. Owing to the presence of differently coordinated fullerene units in compounds 1 and 2, a possible disproportionation of C603– into C602– and C604– anions is discussed. In 3 and 4 the C60 anions are coordinated by three Rb and Cs atoms, respectively. In all compounds the average charge of the anion is –3. Magnetic data reveal a doublet spin state for 3. The EPR spectra are discussed for compounds 3 and 5. The role of a dynamic Jahn-Teller distortion is discussed, and we report the first IR spectroscopic data of fullerene trianions, which have been obtained in solution. |
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| 773 | _ | _ | |a 10.1002/zaac.201300607 |g p. n/a - n/a |0 PERI:(DE-600)1481139-x |n (5) |p 701-712 |t Zeitschrift für anorganische und allgemeine Chemie |v 640 |y 2014 |x 0044-2313 |
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