000152184 001__ 152184
000152184 005__ 20240619092000.0
000152184 0247_ $$2doi$$a10.1021/jp412126n
000152184 0247_ $$2ISSN$$a1520-6106
000152184 0247_ $$2ISSN$$a1520-5207
000152184 0247_ $$2ISSN$$a1089-5647
000152184 0247_ $$2WOS$$aWOS:000333578000023
000152184 037__ $$aFZJ-2014-01958
000152184 041__ $$aEnglish
000152184 082__ $$a530
000152184 1001_ $$0P:(DE-Juel1)144925$$aNaumann, Philipp$$b0$$eCorresponding Author$$ufzj
000152184 245__ $$aIsothermal Behavior of the Soret Effect in Nonionic Microemulsions: Size Variation by Using Different n -Alkanes
000152184 260__ $$aWashington, DC$$bSoc.$$c2014
000152184 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1427179719_12589
000152184 3367_ $$2DataCite$$aOutput Types/Journal article
000152184 3367_ $$00$$2EndNote$$aJournal Article
000152184 3367_ $$2BibTeX$$aARTICLE
000152184 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000152184 3367_ $$2DRIVER$$aarticle
000152184 520__ $$aIn this work we investigate the thermodiffusion behavior of microemulsiondroplets of the type H2O/n-alkane/C12E5 (pentaethylene glycol monododecylether) using the n-alkanes: n-octane, n-decane, n-dodecane, and n-tetradecane. In orderto determine the thermodiffusion behavior of these microemulsion droplets, we applythe infrared thermal diffusion forced Rayleigh scattering (IR-TDFRS) technique. Wemeasure the Soret coefficient (ST) as function of the structure upon approaching theemulsification failure boundary (efb) and as a function of the radius of the spherical o/wmicroemulsion droplets close to the efb. By varying the chain length of the n-alkanes, weare able to study the thermodiffusion behavior of spherical o/w microemulsion dropletsof different sizes at the same temperature. In the investigated range a linear dependenceof the Soret coefficient as function of the radius was found. By use of a proposedrelationship between the Soret coefficient and the temperature dependence of theinterfacial tension, the transition layer l could be determined for the first time.Additionally, small angle neutron scattering (SANS) experiments are performed todetermine the size and to prove that the shape of the microemulsion droplets is spherical close to the efb. Accordingly, thescattering curves could be quantitatively described by a combination of a spherical core−shell form factor and sticky hard spherestructure factor.
000152184 536__ $$0G:(DE-HGF)POF2-451$$a451 - Soft Matter Composites (POF2-451)$$cPOF2-451$$fPOF II$$x0
000152184 536__ $$0G:(GEPRIS)47816710$$aDFG 47816710 - Soret effect in surfactant systems and microemulsions (47816710)$$c47816710$$fDFG SFB TRR6$$x1
000152184 588__ $$aDataset connected to CrossRef, juser.fz-juelich.de
000152184 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0
000152184 65027 $$0V:(DE-MLZ)SciArea-110$$2V:(DE-HGF)$$aChemistry$$x1
000152184 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x2
000152184 65017 $$0V:(DE-MLZ)GC-150-1$$2V:(DE-HGF)$$aKey Technologies$$x1
000152184 65017 $$0V:(DE-MLZ)GC-140$$2V:(DE-HGF)$$aSoft Matter, Macromolecules, Complex fluids, Biophysics $$x0
000152184 693__ $$0EXP:(DE-MLZ)KWS1-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)KWS1-20140101$$6EXP:(DE-MLZ)NL3b-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eKWS-1: Small angle scattering diffractometer$$fNL3b$$x0
000152184 7001_ $$0P:(DE-HGF)0$$aDatta, Sascha$$b1
000152184 7001_ $$0P:(DE-HGF)0$$aSottmann, Thomas$$b2
000152184 7001_ $$0P:(DE-HGF)0$$aArlt, Bastian$$b3
000152184 7001_ $$0P:(DE-Juel1)130646$$aFrielinghaus, Henrich$$b4$$ufzj
000152184 7001_ $$0P:(DE-Juel1)131034$$aWiegand, Simone$$b5$$ufzj
000152184 773__ $$0PERI:(DE-600)2006039-7$$a10.1021/jp412126n$$gVol. 118, no. 12, p. 3451 - 3460$$n12$$p3451 - 3460$$tThe @journal of physical chemistry <Washington, DC> / B$$v118$$x1520-5207$$y2014
000152184 8564_ $$uhttps://juser.fz-juelich.de/record/152184/files/FZJ-2014-01958.pdf$$yRestricted
000152184 909CO $$ooai:juser.fz-juelich.de:152184$$pVDB$$pVDB:MLZ
000152184 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-HGF)0$$aForschungszentrum Jülich GmbH$$b3$$kFZJ
000152184 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130646$$aForschungszentrum Jülich GmbH$$b4$$kFZJ
000152184 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)131034$$aForschungszentrum Jülich GmbH$$b5$$kFZJ
000152184 9132_ $$0G:(DE-HGF)POF3-551$$1G:(DE-HGF)POF3-550$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lBioSoft – Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences$$vFunctional Macromolecules and Complexes$$x0
000152184 9131_ $$0G:(DE-HGF)POF2-451$$1G:(DE-HGF)POF2-450$$2G:(DE-HGF)POF2-400$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bSchlüsseltechnologien$$lBioSoft$$vSoft Matter Composites$$x0
000152184 9141_ $$y2014
000152184 915__ $$0StatID:(DE-HGF)0010$$2StatID$$aJCR/ISI refereed
000152184 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR
000152184 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000152184 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000152184 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000152184 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000152184 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000152184 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000152184 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database
000152184 915__ $$0StatID:(DE-HGF)1020$$2StatID$$aDBCoverage$$bCurrent Contents - Social and Behavioral Sciences
000152184 920__ $$lyes
000152184 9201_ $$0I:(DE-Juel1)ICS-3-20110106$$kICS-3$$lWeiche Materie $$x0
000152184 9201_ $$0I:(DE-Juel1)ICS-1-20110106$$kICS-1$$lNeutronenstreuung $$x1
000152184 9201_ $$0I:(DE-Juel1)JCNS-1-20110106$$kNeutronenstreuung ; JCNS-1$$lNeutronenstreuung $$x2
000152184 9201_ $$0I:(DE-Juel1)JCNS-FRM-II-20110218$$kJCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II$$lJCNS-FRM-II$$x3
000152184 980__ $$ajournal
000152184 980__ $$aVDB
000152184 980__ $$aI:(DE-Juel1)ICS-3-20110106
000152184 980__ $$aI:(DE-Juel1)ICS-1-20110106
000152184 980__ $$aI:(DE-Juel1)JCNS-1-20110106
000152184 980__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000152184 980__ $$aUNRESTRICTED
000152184 981__ $$aI:(DE-Juel1)IBI-8-20200312
000152184 981__ $$aI:(DE-Juel1)JCNS-1-20110106
000152184 981__ $$aI:(DE-Juel1)ICS-1-20110106
000152184 981__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218