% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Naumann:152184,
      author       = {Naumann, Philipp and Datta, Sascha and Sottmann, Thomas and
                      Arlt, Bastian and Frielinghaus, Henrich and Wiegand, Simone},
      title        = {{I}sothermal {B}ehavior of the {S}oret {E}ffect in
                      {N}onionic {M}icroemulsions: {S}ize {V}ariation by {U}sing
                      {D}ifferent n -{A}lkanes},
      journal      = {The journal of physical chemistry / B},
      volume       = {118},
      number       = {12},
      issn         = {1520-5207},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2014-01958},
      pages        = {3451 - 3460},
      year         = {2014},
      abstract     = {In this work we investigate the thermodiffusion behavior of
                      microemulsiondroplets of the type H2O/n-alkane/C12E5
                      (pentaethylene glycol monododecylether) using the n-alkanes:
                      n-octane, n-decane, n-dodecane, and n-tetradecane. In
                      orderto determine the thermodiffusion behavior of these
                      microemulsion droplets, we applythe infrared thermal
                      diffusion forced Rayleigh scattering (IR-TDFRS) technique.
                      Wemeasure the Soret coefficient (ST) as function of the
                      structure upon approaching theemulsification failure
                      boundary (efb) and as a function of the radius of the
                      spherical o/wmicroemulsion droplets close to the efb. By
                      varying the chain length of the n-alkanes, weare able to
                      study the thermodiffusion behavior of spherical o/w
                      microemulsion dropletsof different sizes at the same
                      temperature. In the investigated range a linear dependenceof
                      the Soret coefficient as function of the radius was found.
                      By use of a proposedrelationship between the Soret
                      coefficient and the temperature dependence of theinterfacial
                      tension, the transition layer l could be determined for the
                      first time.Additionally, small angle neutron scattering
                      (SANS) experiments are performed todetermine the size and to
                      prove that the shape of the microemulsion droplets is
                      spherical close to the efb. Accordingly, thescattering
                      curves could be quantitatively described by a combination of
                      a spherical core−shell form factor and sticky hard
                      spherestructure factor.},
      cin          = {ICS-3 / ICS-1 / Neutronenstreuung ; JCNS-1 / JCNS
                      (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ICS-3-20110106 / I:(DE-Juel1)ICS-1-20110106 /
                      I:(DE-Juel1)JCNS-1-20110106 /
                      I:(DE-Juel1)JCNS-FRM-II-20110218},
      pnm          = {451 - Soft Matter Composites (POF2-451) / DFG 47816710 -
                      Soret effect in surfactant systems and microemulsions
                      (47816710)},
      pid          = {G:(DE-HGF)POF2-451 / G:(GEPRIS)47816710},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000333578000023},
      doi          = {10.1021/jp412126n},
      url          = {https://juser.fz-juelich.de/record/152184},
}