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@ARTICLE{Davaasambuu:15284,
author = {Davaasambuu, J. and Güthoff, F. and Hoelzel, M. and
Senyshyn, A. and Radulescu, A. and Eckold, G},
title = {{P}hase {B}ehaviour of {C}o{C}12-{M}n{C}12 {M}ixed
{C}rystals},
journal = {Zeitschrift für Physikalische Chemie},
volume = {225},
issn = {0942-9352},
address = {München},
publisher = {Oldenbourg},
reportid = {PreJuSER-15284},
pages = {413 - 420},
year = {2011},
note = {This work was supported by the DFG under grant EC 153/3-1.},
abstract = {Thermal properties of CoCl2, MnCl2 and their mixed crystals
are investigated by means of temperature dependent neutron
powder diffraction and time-resolved small angle neutron
scattering. The coefficients of thermal expansion of these
crystals have been determined as a function of temperature.
The temperature-induced structural variations can be
explained by distortions of CoCl5/MnCl6 octahedra and
changes in Co/Mn-Cl bond lengths. CoCl2 and MnCl2 form
homogeneous solid solutions in the entire temperature range
between the solidus and 50 K. There is no indication of any
miscibility gap as predicted from thermodynamic
calculations.},
keywords = {J (WoSType)},
cin = {ICS-1 / JCNS (München) ; Jülich Centre for Neutron
Science JCNS (München) ; JCNS-FRM-II / JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)ICS-1-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / Großgeräte für die Forschung
mit Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
experiment = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-MLZ)SPODI-20140101},
shelfmark = {Chemistry, Physical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000290690700003},
doi = {10.1524/zpch.2011.0115},
url = {https://juser.fz-juelich.de/record/15284},
}