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@ARTICLE{Pasel:153237,
      author       = {Pasel, Joachim and Samsun, Remzi Can and Peters, Ralf and
                      Thiele, Björn and Stolten, Detlef},
      title        = {{L}ong-{T}ermin {S}tability at {F}uel {P}rocessing of
                      {D}iesel and {K}erosene},
      journal      = {International journal of hydrogen energy},
      volume       = {39},
      number       = {31},
      issn         = {1879-3487},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2014-02887},
      pages        = {18027 - 18036},
      year         = {2014},
      note         = {POF II: 123, POF III: 135},
      abstract     = {The long-term stability at autothermal reforming of diesel
                      fuel and kerosene was studied using Juelich's autothermal
                      reformer ATR 9.2, which is equipped with a commercial
                      proprietary RhPt/Al2O3–CeO2 catalyst. The experiment was
                      run for 10,000 h of time on stream at constant reaction
                      conditions with an O2/C molar ratio of 0.47, a H2O/C molar
                      ratio of 1.9, and a gas hourly space velocity of 30,000
                      h−1. Kerosene produced via the gas-to-liquid process and
                      diesel fuel synthesized via the bio-to-liquid route were
                      used. Both fuels were almost free of mass fractions of
                      sulfur and aromatics. The trends for the desired main
                      products of autothermal reforming H2, CO, CO2, and CH4 were
                      almost stable when kerosene was used. When the fuel mass
                      flow was switched to diesel fuel however, different modes of
                      catalyst deactivation occurred (active sites blocked by
                      carbonaceous deposits, sintering processes), leading to a
                      decrease in the concentrations of H2 and CO2 with a
                      simultaneous increase in the CO content. This paper defines
                      carbon conversion as the decisive criterion for evaluating
                      the long-term stability during autothermal reforming of
                      kerosene and diesel fuel. Carbon conversion was diminished
                      via three different pathways during the long-term
                      experiment. Undesired byproducts found in the gas phase
                      leaving the reactor had the strongest impact on carbon
                      conversion. These byproducts included ethene, propene, and
                      benzene. Furthermore, a liquid oily residue was detected
                      floating on the condensed unconverted mass flow of water.
                      This happened once during the whole experiment. Finally,
                      undesired organic byproducts were dissolved in the mass flow
                      of unconverted water. These were found to be straight-chain
                      and branched paraffins, esters, alcohols, acids, aldehydes,
                      ketones, etc. Nevertheless, at the end of the long-term
                      experiment, carbon conversion still amounted to more than
                      $98.2\%.$},
      cin          = {IEK-3},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-3-20101013},
      pnm          = {123 - Fuel Cells (POF2-123)},
      pid          = {G:(DE-HGF)POF2-123},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000343781100051},
      doi          = {10.1016/j.ijhydene.2014.03.148},
      url          = {https://juser.fz-juelich.de/record/153237},
}