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@ARTICLE{Cim:153255,
author = {Cimò, Giulia and Kucerik, Jiri and Berns, Anne E. and
Schaumann, Gabriele E. and Alonzo, Giuseppe and Conte,
Pellegrino},
title = {{E}ffect of {H}eating {T}ime and {T}emperature on the
{C}hemical {C}haracteristics of {B}iochar from {P}oultry
{M}anure},
journal = {Journal of agricultural and food chemistry},
volume = {62},
number = {8},
issn = {1520-5118},
address = {Washington, DC [u.a.]},
publisher = {American Chemical Society (ACS)},
reportid = {FZJ-2014-02905},
pages = {1912 - 1918},
year = {2014},
abstract = {Poultry manure (PM) chars were obtained at different
temperatures and charring times. Chemical physical
characterization of the different PM chars was conducted by
cross-polarization magic angle spinning (CPMAS) C-13 NMR
spectroscopy and thermal analysis. CPMAS C-13 NMR spectra
showed that the chemical composition of PM char is dependent
on production temperature rather than on production
duration. Aromatic and alkyl domains in the PM chars
obtained at the lowest temperatures remained unchanged at
all heating times applied for their production. The PM char
obtained at the highest temperature consisted only of
aromatic structures having chemical nature that also
appeared invariant with heating time. Thermogravimetry
revealed differences in the thermo-oxidative stability of
the aromatic domains in the different PM chars. The PM char
produced at the highest temperature appeared less stable
than those produced at the lowest temperatures. This
difference was explained by a protective effect of the alkyl
groups, which are still present in chars formed at lower
temperature. The analysis of the chemical and
physicochemical character of poultry manure chars produced
at different temperatures can increase understanding of the
role of these materials in the properties and behavior of
char-amended soils.},
cin = {IBG-3},
ddc = {630},
cid = {I:(DE-Juel1)IBG-3-20101118},
pnm = {245 - Chemicals in the Environment (POF2-245)},
pid = {G:(DE-HGF)POF2-245},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000332144400023},
doi = {10.1021/jf405549z},
url = {https://juser.fz-juelich.de/record/153255},
}