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@PHDTHESIS{Haydn:153338,
author = {Haydn, Markus},
title = {{E}ntwicklung und {H}erstellung von metallgestützten
{F}estelektrolyt-{B}rennstoffzellen mit {H}ilfe des
{H}ohlkathoden-{G}asflusssputterns},
volume = {180},
school = {Ruhr Universität Bochum},
type = {Dissertation},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2014-02970},
isbn = {978-3-89336-886-0},
series = {Schriften des Forschungszentrums Jülich, Reihe Energie
$\&$ Umwelt / Energy $\&$ Environment},
pages = {XVI, 174 S.},
year = {2013},
note = {Dissertation, Ruhr Universität Bochum, 2013},
abstract = {In this work the electrolyte manufacturing of metal
supported solid oxide fuel cells (MSC) by a gas flow
sputtering (GFS) process is discussed. This GFS process was
developed at Fraunhofer Institute for Surface Engineering
and Thin Films (Fraunhofer IST) in Braunschweig, Germany.
Based on a porous metal substrate (tradename: ITM, Plansee,
Austria) a screen printed anode was developed in cooperation
with Plansee and Forschungszentrum Jülich, Germany. On this
anode a thin and gas-tight electrolyte is brought up by this
physical vapour deposition (PVD) GFS process. The
electrolyte was widely developed on a research facility in
cooperation with Fraunhofer IST whereby a permanent matching
with anode development in Jülich was realized. On the one
hand, a first milestone was to find an anode with a
structure to enable a gas-tight thin film electrolyte and on
the other hand the anode should handle high residual
compressive stresses of that electrolyte. A further
component in this work lied in treatment of occurred
electrolyte coating errors which will increase the leakage
rate of that layer. Hereby different methods were evaluated
which were able to locate coating errors and make them
visible. On the research facility at Fraunhofer IST coating
parameters were worked out and have been transferred to a
manufacturing facility, whereas with this step a first
industrialization was realized. Hereby it was necessary to
ensure a consistent coating thickness and homogeneity of the
electrolyte over the whole coating area. Different MSCs
which were manufactured by an electrolyte depicted within
this work were characterized electrochemically. Hereby
single cell tests in planar design were performed at
Karlsruhe Institute of Technology (KIT), whereas stack tests
of MSCs in cassette design were made in Jülich.},
keywords = {Dissertation (GND)},
cin = {IEK-1},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {123 - Fuel Cells (POF2-123)},
pid = {G:(DE-HGF)POF2-123},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
url = {https://juser.fz-juelich.de/record/153338},
}