000154033 001__ 154033 000154033 005__ 20240610121112.0 000154033 0247_ $$2doi$$a10.3390/polym6051602 000154033 0247_ $$2Handle$$a2128/5839 000154033 0247_ $$2WOS$$aWOS:000337946500015 000154033 037__ $$aFZJ-2014-03447 000154033 082__ $$a540 000154033 1001_ $$0P:(DE-Juel1)136926$$aKobayashi, Hideki$$b0$$ufzj 000154033 245__ $$aStructure of Microgels with Debye-Hückel Interactions 000154033 260__ $$aBasel$$bMDPI$$c2014 000154033 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s154033 000154033 3367_ $$2DataCite$$aOutput Types/Journal article 000154033 3367_ $$00$$2EndNote$$aJournal Article 000154033 3367_ $$2BibTeX$$aARTICLE 000154033 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000154033 3367_ $$2DRIVER$$aarticle 000154033 520__ $$aThe structural properties of model microgel particles are investigated by molecular dynamics simulations applying a coarse-grained model. A microgel is comprised of a regular network of polymers internally connected by tetra-functional cross-links and with dangling ends at its surface. The self-avoiding polymers are modeled as bead-spring linear chains. Electrostatic interactions are taken into account by the Debye–Hückel potential. The microgels exhibit a quite uniform density under bad solvent conditions with a rather sharp surface. With increasing Debye length, structural inhomogeneities appear, their surface becomes fuzzy and, at very large Debye lengths, well defined again. Similarly, the polymer conformations change from a self-avoiding walk to a rod-like behavior. Thereby, the average polymer radius of gyration follows a scaling curve in terms of polymer length and persistence length, with an asymptotic rod-like behavior for swollen microgels and self-avoiding walk behavior for weakly swollen gel particles. 000154033 536__ $$0G:(DE-HGF)POF2-451$$a451 - Soft Matter Composites (POF2-451)$$cPOF2-451$$fPOF II$$x0 000154033 7001_ $$0P:(DE-Juel1)131039$$aWinkler, Roland G.$$b1$$ufzj 000154033 773__ $$0PERI:(DE-600)2527146-5$$a10.3390/polym6051602$$n5$$p1602-1617$$tPolymers$$v6$$x2073-4360$$y2014 000154033 8564_ $$uhttps://juser.fz-juelich.de/record/154033/files/FZJ-2014-03447.pdf$$yOpenAccess 000154033 8564_ $$uhttps://juser.fz-juelich.de/record/154033/files/FZJ-2014-03447.jpg?subformat=icon-144$$xicon-144$$yOpenAccess 000154033 8564_ $$uhttps://juser.fz-juelich.de/record/154033/files/FZJ-2014-03447.jpg?subformat=icon-180$$xicon-180$$yOpenAccess 000154033 8564_ $$uhttps://juser.fz-juelich.de/record/154033/files/FZJ-2014-03447.jpg?subformat=icon-640$$xicon-640$$yOpenAccess 000154033 8767_ $$92014-05-19$$d2014-05-21$$eAPC$$jZahlung erfolgt$$zCHF 1200,- 000154033 909CO $$ooai:juser.fz-juelich.de:154033$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$pOpenAPC$$popen_access$$popenaire 000154033 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)136926$$aForschungszentrum Jülich GmbH$$b0$$kFZJ 000154033 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)131039$$aForschungszentrum Jülich GmbH$$b1$$kFZJ 000154033 9132_ $$0G:(DE-HGF)POF3-551$$1G:(DE-HGF)POF3-550$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lBioSoft Fundamentals for future Technologies in the fields of Soft Matter and Life Sciences$$vFunctional Macromolecules and Complexes$$x0 000154033 9131_ $$0G:(DE-HGF)POF2-451$$1G:(DE-HGF)POF2-450$$2G:(DE-HGF)POF2-400$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bSchlüsseltechnologien$$lBioSoft$$vSoft Matter Composites$$x0 000154033 9141_ $$y2014 000154033 915__ $$0LIC:(DE-HGF)CCBY3$$2HGFVOC$$aCreative Commons Attribution CC BY 3.0 000154033 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess 000154033 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline 000154033 915__ $$0StatID:(DE-HGF)0040$$2StatID$$aPeer review unknown 000154033 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ 000154033 9201_ $$0I:(DE-Juel1)IAS-2-20090406$$kIAS-2$$lTheorie der Weichen Materie und Biophysik $$x0 000154033 9201_ $$0I:(DE-Juel1)ICS-2-20110106$$kICS-2$$lTheorie der Weichen Materie und Biophysik $$x1 000154033 9801_ $$aFullTexts 000154033 980__ $$ajournal 000154033 980__ $$aVDB 000154033 980__ $$aUNRESTRICTED 000154033 980__ $$aFullTexts 000154033 980__ $$aI:(DE-Juel1)IAS-2-20090406 000154033 980__ $$aI:(DE-Juel1)ICS-2-20110106 000154033 980__ $$aAPC 000154033 981__ $$aI:(DE-Juel1)IBI-5-20200312 000154033 981__ $$aI:(DE-Juel1)IAS-2-20090406 000154033 981__ $$aI:(DE-Juel1)ICS-2-20110106