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@INBOOK{Winkler:154037,
      author       = {Winkler, Roland G. and Cherstvy, Andrey},
      title        = {{S}trong and {W}eak {P}olyelectrolyte {A}dsorption onto
                      {O}ppositely {C}harged {C}urved {S}urfaces},
      journal      = {Advances in polymer science},
      volume       = {255},
      issn         = {1436-5030},
      address      = {Berlin},
      publisher    = {Springer},
      reportid     = {FZJ-2014-03451},
      pages        = {1-56},
      year         = {2014},
      comment      = {Polyelectrolyte Complexes in the Dispersed and Solid State
                      I},
      booktitle     = {Polyelectrolyte Complexes in the
                       Dispersed and Solid State I},
      abstract     = {Polyelectrolytes are macromolecules composed of charged
                      monomers and exhibit unique properties due to the interplay
                      of their flexibility and electrostatic interactions. In
                      solution, they are attracted to oppositely charged surfaces
                      and interfaces and exhibit a transition to an adsorbed state
                      when certain conditions are met concerning the charge
                      densities of the polymer and surface and the properties of
                      the solution. In this review, we discuss two limiting cases
                      for adsorption of flexible polyelectrolytes on curved
                      surfaces: weak and strong adsorption. In the first case,
                      adsorption is strongly influenced by the entropic degrees of
                      freedom of a flexible polyelectrolyte. By contrast, in the
                      strong adsorption limit, electrostatic interactions
                      dominate, which leads to particular adsorption patterns,
                      specifically on spherical surfaces. We discuss the
                      corresponding theoretical approaches, applying a mean-field
                      description for the polymer and the polymer–surface
                      interaction. For weak adsorption, we discuss the critical
                      adsorption behavior by exactly solvable models for planar
                      and spherical geometries and a generic approximation scheme,
                      which is additionally applied to cylindrical surfaces. For
                      strong adsorption, we investigate various polyelectrolyte
                      patterns on cylinders and spheres and evaluate their
                      stability. The results are discussed in the light of
                      experimental results, mostly of DNA adsorption experiments},
      cin          = {IAS-2 / ICS-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IAS-2-20090406 / I:(DE-Juel1)ICS-2-20110106},
      pnm          = {451 - Soft Matter Composites (POF2-451)},
      pid          = {G:(DE-HGF)POF2-451},
      typ          = {PUB:(DE-HGF)7},
      UT           = {WOS:000335194800002},
      doi          = {10.1007/12_2012_183},
      url          = {https://juser.fz-juelich.de/record/154037},
}