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000154049 041__ $$aEnglish
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000154049 1001_ $$0P:(DE-HGF)0$$aVasylyev, Olexsandr$$b0
000154049 245__ $$aNucleation and Growth Mechainsms of Zirconia Film Deposited on Porous Nickel Oxide - Zirconia Substrate by Electron Beam - Physical Vapor Deposition
000154049 260__ $$aRiley, Ind.$$bScience and Engineering Publishing Company (SEP)$$c2014
000154049 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1417708532_21916
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000154049 520__ $$aThe structure of the transitional zone between a zirconia film deposited by EB-PVD and its porous NiO-ZrO2 substrate were studied using transmission and scanning electron microscopy. The plausible condensation mechanisms of zirconia from its vapor phase onto zirconia and nickel oxide phases of the substrate were established. The condensation of zirconia was identified as a two-stage process with two mechanisms of growth, planar and cellular, similar to solidification from the liquid phase. ZrO2 condensation on ZrO2 and NiO phases occurs with different routes. During the planar growth on the ZrO2, the ZrO2 film nucleates and grows up to ~0.3-0.5 μm with no orientation preference as continuous "layer by layer" defective film. The planar ZrO2 film on the NiO of ~0.5-0.7 μm thickness is discontinuous and porous; it consists of oriented structurally perfect "islands". The differences found are probably the result of differences in the melting temperature of ZrO2 and NiO, and Zr and Ni affinities to oxygen as well as their different behavior under high vacuum. The deposition affected zone surrounding the ZrO2 nucleation site is established.Keywords: Zirconia Film; Nucleation Mechanism; Growth Mechanism; Thin Structure; Solid Oxide Fuel Cell; Electron Beam – Physical Vapor Deposition
000154049 536__ $$0G:(DE-HGF)POF2-123$$a123 - Fuel Cells (POF2-123)$$cPOF2-123$$fPOF II$$x0
000154049 536__ $$0G:(DE-HGF)POF2-152$$a152 - Renewable Energies (POF2-152)$$cPOF2-152$$fPOF II$$x1
000154049 7001_ $$0P:(DE-HGF)0$$aBrychevskyi, Mykola$$b1
000154049 7001_ $$0P:(DE-HGF)0$$aBrodnikovskyi, Iegor$$b2
000154049 7001_ $$0P:(DE-HGF)0$$aFirstov, Sergiy$$b3
000154049 7001_ $$0P:(DE-HGF)0$$aAndrzejczuk, Mariusz$$b4
000154049 7001_ $$0P:(DE-HGF)0$$aSpychalski, Maciek$$b5
000154049 7001_ $$0P:(DE-HGF)0$$aLewandowska, Malgorzata$$b6
000154049 7001_ $$0P:(DE-HGF)0$$aKurzydlowski, Krzysztof Jan$$b7
000154049 7001_ $$0P:(DE-HGF)0$$aSteinberger-Wilckens, Robert$$b8
000154049 7001_ $$0P:(DE-Juel1)130445$$aMertens, Josef$$b9$$ufzj
000154049 7001_ $$0P:(DE-Juel1)129755$$aMalzbender, Jürgen$$b10$$ufzj
000154049 773__ $$0PERI:(DE-600)2703787-3$$n2014$$p25-35$$tAdvances in Ceramic Science and Engineering$$v3$$x2325-5129$$y2014
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000154049 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130445$$aForschungszentrum Jülich GmbH$$b9$$kFZJ
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000154049 9132_ $$0G:(DE-HGF)POF3-131$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$aDE-HGF$$bForschungsbereich Energie$$lSpeicher und vernetzte Infrastrukturen$$vElectrochemical Storage$$x0
000154049 9132_ $$0G:(DE-HGF)POF3-135$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$aDE-HGF$$bForschungsbereich Energie$$lSpeicher und vernetzte Infrastrukturen$$vFuel Cells$$x1
000154049 9131_ $$0G:(DE-HGF)POF2-123$$1G:(DE-HGF)POF2-120$$2G:(DE-HGF)POF2-100$$3G:(DE-HGF)POF2$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lRationelle Energieumwandlung und -nutzung$$vFuel Cells$$x0
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000154049 9141_ $$y2014
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000154049 9201_ $$0I:(DE-Juel1)IEK-9-20110218$$kIEK-9$$lGrundlagen der Elektrochemie$$x0
000154049 9201_ $$0I:(DE-Juel1)IEK-2-20101013$$kIEK-2$$lWerkstoffstruktur und -eigenschaften$$x1
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