Hauptseite > Publikationsdatenbank > Influence of stoichiometry on the performance of MIM capacitors from plasma-assisted ALD Sr x Ti y O z films > print |
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100 | 1 | _ | |a Aslam, N. |0 P:(DE-Juel1)140489 |b 0 |e Corresponding Author |u fzj |
245 | _ | _ | |a Influence of stoichiometry on the performance of MIM capacitors from plasma-assisted ALD Sr x Ti y O z films |
260 | _ | _ | |a Weinheim |c 2014 |b Wiley-VCH |
336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1403102517_30228 |2 PUB:(DE-HGF) |
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520 | _ | _ | |a Strontium titanate, SrxTiyOz (STO), thin films with various cation stoichiometries were deposited by plasma-assisted atomic layer deposition (ALD) using cyclopentadienyl-based metal precursors and oxygen plasma as counter-reactant. [Sr]/([Sr] + [Ti]) compositions ranging from 0.46 to 0.57 were obtained by changing the (SrO)/(TiO2) ALD cycle ratios. As-deposited 15–30 nm thick SrxTiyOz films prepared at 350 °C on Pt-coated silicon substrates were amorphous. Post-annealing at 600/650 °C for 10 min under N2 gas resulted in a crystallization into the perovskite phase. Stoichiometric STO and Sr-rich STO films exhibited a certain degree of (111) texture while the Ti-rich STO films showed a lower degree of crystallization. Crystallized layers exhibited a smaller band gap Eg than amorphous ones, while within the stoichiometry series the value of Eg increased with increasing Sr-content. Within the stoichiometry series Pt/STO/Pt structures with Sr-rich STO films showed the lowest leakage current densities. At 1.0 V values of about 2 × 10−8 and 5 × 10−6 A cm−2 were obtained for the as-deposited and the annealed films, respectively. Highest capacitance density was obtained for 15 nm polycrystalline stoichiometric SrTiO3 films resulting in a capacitor equivalent thickness CET of about 0.7 nm. Pt/SrxTiyOz/Pt capacitors with the STO being in amorphous state exhibited a positive voltage nonlinearity factor α of about 400 ppm V−2, while the negative α-values for crystallized films showed a systematic variation with the stoichiometry, the degree of crystallization and the thickness of the STO layer. This demonstrates that a broad performance range of MIM capacitors is accessible by controlling the stoichiometry and the degree of crystallization of plasma-assisted ALD SrxTiyOz thin films. |
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773 | _ | _ | |a 10.1002/pssa.201330101 |g Vol. 211, no. 2, p. 389 - 396 |0 PERI:(DE-600)1481091-8 |n 2 |p 389 - 396 |t Physica status solidi / A |v 211 |y 2014 |x 1862-6300 |
856 | 4 | _ | |u https://juser.fz-juelich.de/record/154093/files/FZJ-2014-03495.pdf |z Published final document. |y Restricted |
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