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024 7 _ |a 10.1002/pssa.201330101
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024 7 _ |a 1862-6319
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024 7 _ |a 0031-8965
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024 7 _ |a 1862-6300
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024 7 _ |a 1521-396X
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037 _ _ |a FZJ-2014-03495
082 _ _ |a 530
100 1 _ |a Aslam, N.
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245 _ _ |a Influence of stoichiometry on the performance of MIM capacitors from plasma-assisted ALD Sr x Ti y O z films
260 _ _ |a Weinheim
|c 2014
|b Wiley-VCH
336 7 _ |a Journal Article
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520 _ _ |a Strontium titanate, SrxTiyOz (STO), thin films with various cation stoichiometries were deposited by plasma-assisted atomic layer deposition (ALD) using cyclopentadienyl-based metal precursors and oxygen plasma as counter-reactant. [Sr]/([Sr] + [Ti]) compositions ranging from 0.46 to 0.57 were obtained by changing the (SrO)/(TiO2) ALD cycle ratios. As-deposited 15–30 nm thick SrxTiyOz films prepared at 350 °C on Pt-coated silicon substrates were amorphous. Post-annealing at 600/650 °C for 10 min under N2 gas resulted in a crystallization into the perovskite phase. Stoichiometric STO and Sr-rich STO films exhibited a certain degree of (111) texture while the Ti-rich STO films showed a lower degree of crystallization. Crystallized layers exhibited a smaller band gap Eg than amorphous ones, while within the stoichiometry series the value of Eg increased with increasing Sr-content. Within the stoichiometry series Pt/STO/Pt structures with Sr-rich STO films showed the lowest leakage current densities. At 1.0 V values of about 2 × 10−8 and 5 × 10−6 A cm−2 were obtained for the as-deposited and the annealed films, respectively. Highest capacitance density was obtained for 15 nm polycrystalline stoichiometric SrTiO3 films resulting in a capacitor equivalent thickness CET of about 0.7 nm. Pt/SrxTiyOz/Pt capacitors with the STO being in amorphous state exhibited a positive voltage nonlinearity factor α of about 400 ppm V−2, while the negative α-values for crystallized films showed a systematic variation with the stoichiometry, the degree of crystallization and the thickness of the STO layer. This demonstrates that a broad performance range of MIM capacitors is accessible by controlling the stoichiometry and the degree of crystallization of plasma-assisted ALD SrxTiyOz thin films.
536 _ _ |a 424 - Exploratory materials and phenomena (POF2-424)
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588 _ _ |a Dataset connected to CrossRef, juser.fz-juelich.de
700 1 _ |a Longo, V.
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700 1 _ |a Keuning, W.
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700 1 _ |a Roozeboom, F.
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700 1 _ |a Kessels, W. M. M.
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700 1 _ |a Waser, R.
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700 1 _ |a Hoffmann-Eifert, S.
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773 _ _ |a 10.1002/pssa.201330101
|g Vol. 211, no. 2, p. 389 - 396
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|t Physica status solidi / A
|v 211
|y 2014
|x 1862-6300
856 4 _ |u https://juser.fz-juelich.de/record/154093/files/FZJ-2014-03495.pdf
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909 C O |o oai:juser.fz-juelich.de:154093
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