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@ARTICLE{Wiener:154294,
author = {Wießner, M. and Hauschild, D. and Sauer, C. and Feyer, V.
and Schöll, A. and Reinert, F.},
title = {{C}omplete determination of molecular orbitals by
measurement of phase symmetry and electron density},
journal = {Nature Communications},
volume = {5},
issn = {2041-1723},
address = {London},
publisher = {Nature Publishing Group},
reportid = {FZJ-2014-03651},
pages = {4156},
year = {2014},
abstract = {Several experimental methods allow measuring the spatial
probability density of electrons in atoms, molecules and
solids, that is, the absolute square of the respective
single-particle wave function. But it is an intrinsic
problem of the measurement process that the information
about the phase is generally lost during the experiment. The
symmetry of this phase, however, is a crucial parameter for
the knowledge of the full orbital information in real space.
Here, we report on a key experiment that demonstrates that
the phase symmetry can be derived from a strictly
experimental approach from the circular dichroism in the
angular distribution of photoelectrons. In combination with
the electron density derived from the same experiment, the
full quantum mechanical wave function can thus be determined
experimentally},
cin = {PGI-6 / JARA-FIT},
ddc = {500},
cid = {I:(DE-Juel1)PGI-6-20110106 / $I:(DE-82)080009_20140620$},
pnm = {422 - Spin-based and quantum information (POF2-422)},
pid = {G:(DE-HGF)POF2-422},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000338838500012},
pubmed = {pmid:24910256},
doi = {10.1038/ncomms5156},
url = {https://juser.fz-juelich.de/record/154294},
}