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@ARTICLE{Egger:154441,
author = {Egger, H. and Findenegg, G. H. and Holderer, O. and Biehl,
R. and Monkenbusch, M. and Hellweg, T.},
title = {{B}ending elastic properties of a block copolymer-rich
lamellar phase doped by a surfactant: a neutron spin-echo
study},
journal = {Soft matter},
volume = {10},
number = {36},
issn = {1744-6848},
address = {Cambridge},
publisher = {Royal Society of Chemistry (RSC)},
reportid = {FZJ-2014-03788},
pages = {6926-6930},
year = {2014},
abstract = {The influence of the short alkyl-chain ionic surfactant
OTAB on the dynamic behavior of an inverse block
copolymer-rich lamellar phase was investigated by neutron
spin-echo spectroscopy (NSE). The observed intermediate
scattering function can be described by a sum of two
contributions. For high scattering vectors the model of
Zilman–Granek plus a slow diffusional mode can be used to
describe the experimental data and the bending elastic
modulus κ for a polymer-rich membrane is calculated. At low
scattering vectors the relaxation curves are strongly
influenced by de Gennes narrowing arising from the structure
factor of the Lα phase. Hence, the computed relaxation
rates in this q-range are inversely proportional to the
static structure factor. The present study demonstrates the
necessity to directly investigate the dynamic behavior of
lamellar phases and that an analysis of the width of the
Bragg peaks can be insufficient to derive information about
the single membrane elasticity, especially when both κ and
[B with combining macron] depend on the composition of the
membrane.},
cin = {Neutronenstreuung ; JCNS-1 / JCNS (München) ; Jülich
Centre for Neutron Science JCNS (München) ; JCNS-FRM-II /
ICS-1},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)ICS-1-20110106},
pnm = {451 - Soft Matter Composites (POF2-451) / 54G - JCNS
(POF2-54G24)},
pid = {G:(DE-HGF)POF2-451 / G:(DE-HGF)POF2-54G24},
experiment = {EXP:(DE-MLZ)J-NSE-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000341025700006},
doi = {10.1039/c4sm00494a},
url = {https://juser.fz-juelich.de/record/154441},
}