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@INPROCEEDINGS{Wang:154519,
author = {Wang, Zilin and Afanasenkau, Dzmitry and Wiegand, Simone},
title = {{M}olar mass and temperature dependence of the
thermodifusion of polyethylene oxide in water/ethanol
mixtures},
school = {University of Cologne},
reportid = {FZJ-2014-03833},
year = {2014},
abstract = {In this work we study the molar mass dependence of the
thermodiffusion of polyethylene oxide atdifferent
temperatures in water, ethanol and in a water/ethanol
mixture $(C_water$ = 0.7) in a molar massrange up to
Mw=180000 g/mol. Due to the low solubility of polyethylene
oxide oligomers in ethanol themeasurements are limited up to
Mw=2200 g/mol. The specific water/ethanol concentration 0.7
is chosen,because at this weight fraction the thermal
diffusion coefficient, $D_T,$ of water/ethanol vanishes so
thatthe system can be treated as a pseudo binary mixtures.
The addition of ethanol will degrade the solventquality, so
that we expect a change in the interaction energies, which
can be calculated using a modelderived by Würger [1]. We
also found that with adding ethanol to water, the
thermodiffusion behavior ofPEO changes from thermophobic to
thermophilic.},
month = {Jun},
date = {2014-06-02},
organization = {11th International Meeting on
Thermodiffusion, Bayonne (France), 2
Jun 2014 - 6 Jun 2014},
subtyp = {After Call},
cin = {ICS-3},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {451 - Soft Matter Composites (POF2-451)},
pid = {G:(DE-HGF)POF2-451},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/154519},
}