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@ARTICLE{Klein:15469,
      author       = {Klein, M. and Wiegand, S.},
      title        = {{T}he {S}oret effect of mono-, di- and tri-glycols in
                      ethanol},
      journal      = {Physical Chemistry Chemical Physics},
      volume       = {13},
      issn         = {1463-9076},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {PreJuSER-15469},
      pages        = {7090 - 7094},
      year         = {2011},
      note         = {We would like to thank Pablo Blanco and Bastian Arlt for
                      many fruitful discussions and Hartmut Kriegs for technical
                      support. Financial support due to the Deutsche
                      Forschungsgemeinschaft grant Wi 1684 is gratefully
                      acknowledged.},
      abstract     = {We employed thermal diffusion forced Rayleigh scattering
                      (TDFRS) to investigate the chain length dependence of the
                      thermal diffusion behavior of short glycols in ethanol. We
                      studied three glycols, monoethylenglycol (MEG),
                      diethylenglycol (DEG) and triethylenglycol (TEG), in an
                      ethanol solution. In contrast to the polymer
                      polyethylenglycol, the shorter glycols used within the
                      framework of this study are completely soluble in ethanol,
                      at least for low molar fractions. In order to guarantee a
                      good solubility of the glycols, the measurements were
                      limited to molar fractions of $10\%$ and $20\%.$ As the
                      different glycols only differ by their chain length it will
                      be possible to deduce its influence on the thermal diffusion
                      properties. Due to the fairly short persistence length of
                      the glycols, D(T) reaches already for the dimer a plateau
                      value. This finding agrees with simulation results.
                      Furthermore, the thermal expansion and the kinematic
                      viscosity are measured to investigate if empirical
                      correlations seen for other systems could be confirmed.},
      keywords     = {J (WoSType)},
      cin          = {ICS-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-3-20110106},
      pnm          = {BioSoft: Makromolekulare Systeme und biologische
                      Informationsverarbeitung},
      pid          = {G:(DE-Juel1)FUEK505},
      shelfmark    = {Chemistry, Physical / Physics, Atomic, Molecular $\&$
                      Chemical},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:21409281},
      UT           = {WOS:000288951000035},
      doi          = {10.1039/c1cp00022e},
      url          = {https://juser.fz-juelich.de/record/15469},
}