Hauptseite > Publikationsdatenbank > Fading of modern Prussian blue pigments in linseed oil medium > print

001     15471
005     20240529111747.0
024 7 _ |2 DOI
|a 10.1039/c0ja00234h
024 7 _ |2 WOS
|a WOS:000289731900008
024 7 _ |2 Handle
|a 2128/7294
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037 _ _ |a PreJuSER-15471
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Analytical
084 _ _ |2 WoS
|a Spectroscopy
100 1 _ |0 P:(DE-HGF)0
|a Samain, L.
|b 0
245 _ _ |a Fading of modern Prussian blue pigments in linseed oil medium
260 _ _ |a Cambridge
|b ChemSoc
|c 2011
300 _ _ |a 930 - 941
336 7 _ |a Journal Article
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440 _ 0 |0 3023
|a Journal of Analytical Atomic Spectrometry
|v 26
|x 0267-9477
|y 5
500 _ _ |a The financial support of the Fonds National de la Recherche Scientifique (F.R.S-FNRS), Belgium (grants 9.456595 and 1.5.064.05), is gratefully acknowledged. This work is supported by the Belgian inter-university Attraction Pole Program P6/16 Belgian State Belgian Science Policy. G. Silversmit is supported by a postdoctoral fellowship from the Research Foundation-Flanders (FWO-Vlaanderen, Belgium).
520 _ _ |a The fading of modern laboratory-synthesized and commercial Prussian blue, iron(III) hexacyanoferrate (II), based pigments in a linseed oil medium during exposure to light has been investigated. The Prussian blue pigments were painted with linseed oil, as a pure pigment and mixed with white lead, (PbCO3)(2)Pb (OH)(2), zinc white, ZnO, or titanium white, TiO2, pigment. The samples were subjected to accelerated ageing for 800 h and the light fastness of the Prussian blue pigment was evaluated by reference to blue wool standards. Pure Prussian blue is extremely light fast whilst it strongly fades when mixed with a white pigment, especially with lead white or zinc oxide. The painted samples were studied by UV-visible, iron K-edge X-ray absorption, iron-57 transmission Mossbauer, and attenuated total reflectance infrared spectroscopy. X-ray absorption results reveal a decrease in the iron coordination number in aged samples in the presence of white pigment. The Mossbauer spectra of the pure Prussian blue and the unaged and aged mixtures of Prussian blue and lead white or zinc oxide at 1 : 100 and 1 : 10 dilution ratios, respectively, indicate the presence of iron(II) and iron(III) in a ratio close to one as expected for the bulk stoichiometric KFeIII[Fe-II(CN)(6)]; no change in the spectral parameters was observed upon ageing. Combined with the X-ray near edge absorption and infrared studies, these results suggest reduction of the surface iron ions in the Prussian blue with ageing upon exposure to light.
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|a Silversmit, G.
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|a Sanyova, J.
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|a Vekemans, B.
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|a Salomon, H.
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|a Gilbert, B.
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|a Grandjean, F.
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700 1 _ |0 P:(DE-HGF)0
|a Long, G. L.
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|a Strivay, D.
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|a 10.1039/c0ja00234h
|g Vol. 26, p. 930 - 941
|p 930 - 941
|q 26<930 - 941
|t Journal of analytical atomic spectrometry
|v 26
|x 0267-9477
|y 2011
856 7 _ |u http://dx.doi.org/10.1039/c0ja00234h
856 4 _ |u https://juser.fz-juelich.de/record/15471/files/FZJ-15471.pdf
|y Published under German "Allianz" Licensing conditions on 2011-04-08. Available in OpenAccess from 2012-04-08
|z Published final document.
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