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000154972 0247_ $$2doi$$a10.1016/j.electacta.2013.07.112
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000154972 037__ $$aFZJ-2014-04181
000154972 041__ $$aEnglish
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000154972 1001_ $$0P:(DE-HGF)0$$aRuderman, A.$$b0$$eCorresponding Author
000154972 245__ $$aCurrent transients for the hydrogen evolution reaction at high overpotentials on silver electrodes in acid solutions: Experiments and modelling
000154972 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2013
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000154972 520__ $$aThe hydrogen evolution reaction has been investigated on Ag(1 0 0) by potentiostatic current transients at high overpotentials (η > 0.7 V) in acidic solutions. The reaction proceeds via the Volmer–Heyrovsky mechanism, simultaneously coupled with desorption of sulphate/disulphate anions. Volmer is the rate determined step, although the Heyrovsky reaction is only slightly faster. The kinetic parameters have been obtained under various conditions of pH and concentration of anions. A catalytic effect due to the presence of anions has been observed.
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000154972 7001_ $$0P:(DE-HGF)0$$aJuarez, M. F.$$b1
000154972 7001_ $$0P:(DE-HGF)0$$aSoldano, G.$$b2
000154972 7001_ $$0P:(DE-HGF)0$$aAvalle, L. B.$$b3
000154972 7001_ $$0P:(DE-Juel1)128800$$aBeltramo, G.$$b4$$ufzj
000154972 7001_ $$0P:(DE-Juel1)159441$$aGiesen, M.$$b5$$ufzj
000154972 7001_ $$0P:(DE-HGF)0$$aSantos, E.$$b6
000154972 773__ $$0PERI:(DE-600)1483548-4$$a10.1016/j.electacta.2013.07.112$$gVol. 109, p. 403 - 410$$p403 - 410$$tElectrochimica acta$$v109$$x0013-4686$$y2013
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