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@ARTICLE{Ruderman:154972,
      author       = {Ruderman, A. and Juarez, M. F. and Soldano, G. and Avalle,
                      L. B. and Beltramo, G. and Giesen, M. and Santos, E.},
      title        = {{C}urrent transients for the hydrogen evolution reaction at
                      high overpotentials on silver electrodes in acid solutions:
                      {E}xperiments and modelling},
      journal      = {Electrochimica acta},
      volume       = {109},
      issn         = {0013-4686},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2014-04181},
      pages        = {403 - 410},
      year         = {2013},
      abstract     = {The hydrogen evolution reaction has been investigated on
                      Ag(1 0 0) by potentiostatic current transients at high
                      overpotentials (η > 0.7 V) in acidic solutions. The
                      reaction proceeds via the Volmer–Heyrovsky mechanism,
                      simultaneously coupled with desorption of
                      sulphate/disulphate anions. Volmer is the rate determined
                      step, although the Heyrovsky reaction is only slightly
                      faster. The kinetic parameters have been obtained under
                      various conditions of pH and concentration of anions. A
                      catalytic effect due to the presence of anions has been
                      observed.},
      cin          = {ICS-7},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-7-20110106},
      pnm          = {453 - Physics of the Cell (POF2-453)},
      pid          = {G:(DE-HGF)POF2-453},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000328006300057},
      doi          = {10.1016/j.electacta.2013.07.112},
      url          = {https://juser.fz-juelich.de/record/154972},
}