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@ARTICLE{Lazi:155068,
author = {Lazić, Predrag and Caciuc, Vasile and Atodiresei, Nicolae
and Callsen, Martin and Blügel, Stefan},
title = {{F}irst-principles insights into the electronic and
magnetic structure of hybrid organic-metal interfaces},
journal = {Journal of physics / Condensed matter},
volume = {26},
number = {26},
issn = {1361-648X},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2014-04253},
pages = {263001},
year = {2014},
abstract = {In this review we summarize our experience gained from
several recent ab initio studies aimed to investigate how
the competition between short-ranged chemical and
long-ranged dispersion interactions determines the bonding
mechanism of a specific set of chemically functionalized
π-conjugated organic molecules on non-magnetic and magnetic
metal surfaces. A key point of this review is to provide a
detailed analysis on the issue of how to tune the strength
of the organic molecule-surface interaction, such that the
nature of the molecular bonding exhibits the specific
electronic features of the physisorption or chemisorption
bonding mechanisms. In particular, we discuss in detail how
the precise control of these bonding mechanisms can be used
to design specific electronic and magnetic properties of
hybrid organic-metallic interfaces. Furthermore, our
first-principles simulations provide not only the basic
insights needed to interpret surface-science experiments,
but are also a key tool to design organic-substrate systems
with tailored properties that can be integrated into future
organic-based devices for molecular electronics and
molecular spintronics applications.},
cin = {IAS-1 / PGI-1},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106},
pnm = {422 - Spin-based and quantum information (POF2-422)},
pid = {G:(DE-HGF)POF2-422},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000337349200002},
doi = {10.1088/0953-8984/26/26/263001},
url = {https://juser.fz-juelich.de/record/155068},
}