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000155181 0247_ $$2doi$$a10.1016/j.jpowsour.2014.07.189
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000155181 041__ $$aEnglish
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000155181 1001_ $$0P:(DE-HGF)0$$aGarcia-Fresnillo, L.$$b0
000155181 245__ $$aLong-term behaviour of solid oxide fuel cell interconnect materials in contact with Ni-mesh during exposure in simulated anode gas at 700 and 800°C
000155181 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2014
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000155181 520__ $$aIn the present study the long-term behaviour of two ferritic steels, Crofer 22 APU and Crofer 22H, in contact with a Ni-mesh during exposure in simulated anode gas, Ar–4%H2–2%H2O, at 700 and 800 °C for exposure times up to 3000 h was investigated. Ni diffusion from the Ni-mesh into the steel resulted in the formation of an austenitic zone whereas diffusion of iron and chromium from the steel into the Ni-mesh resulted in the formation of chromia base oxides in the Ni-mesh. Depending on the chemical composition of the steel, the temperature and the exposure time, interdiffusion processes between ferritic steel and Ni-mesh also resulted in σ-phase formation at the austenite–ferrite interface and in Laves-phase dissolution in the austenitic zone. The extent and morphology of the σ-phase formation are discussed on the basis of thermodynamic considerations, including reaction paths in the ternary alloy system Fe–Ni–Cr.
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000155181 7001_ $$0P:(DE-Juel1)129794$$aShemet, V.$$b1
000155181 7001_ $$0P:(DE-Juel1)129701$$aChyrkin, A.$$b2$$eCorresponding Author
000155181 7001_ $$0P:(DE-Juel1)129952$$ade Haart, L. G. J.$$b3
000155181 7001_ $$0P:(DE-Juel1)129782$$aQuadakkers, W. J.$$b4
000155181 773__ $$0PERI:(DE-600)1491915-1$$a10.1016/j.jpowsour.2014.07.189$$gp. S0378775314012531$$n20$$p213-222$$tJournal of power sources$$v271$$x0378-7753$$y2014
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