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005     20240712112830.0
024 7 _ |a 10.1016/j.jpowsour.2014.07.189
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024 7 _ |a 0378-7753
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024 7 _ |a 1873-2755
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037 _ _ |a FZJ-2014-04362
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100 1 _ |a Garcia-Fresnillo, L.
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245 _ _ |a Long-term behaviour of solid oxide fuel cell interconnect materials in contact with Ni-mesh during exposure in simulated anode gas at 700 and 800°C
260 _ _ |a New York, NY [u.a.]
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336 7 _ |a Journal Article
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520 _ _ |a In the present study the long-term behaviour of two ferritic steels, Crofer 22 APU and Crofer 22H, in contact with a Ni-mesh during exposure in simulated anode gas, Ar–4%H2–2%H2O, at 700 and 800 °C for exposure times up to 3000 h was investigated. Ni diffusion from the Ni-mesh into the steel resulted in the formation of an austenitic zone whereas diffusion of iron and chromium from the steel into the Ni-mesh resulted in the formation of chromia base oxides in the Ni-mesh. Depending on the chemical composition of the steel, the temperature and the exposure time, interdiffusion processes between ferritic steel and Ni-mesh also resulted in σ-phase formation at the austenite–ferrite interface and in Laves-phase dissolution in the austenitic zone. The extent and morphology of the σ-phase formation are discussed on the basis of thermodynamic considerations, including reaction paths in the ternary alloy system Fe–Ni–Cr.
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700 1 _ |a Shemet, V.
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700 1 _ |a Chyrkin, A.
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700 1 _ |a de Haart, L. G. J.
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700 1 _ |a Quadakkers, W. J.
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773 _ _ |a 10.1016/j.jpowsour.2014.07.189
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|t Journal of power sources
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