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@ARTICLE{Wang:155214,
      author       = {Wang, Zilin and Afanasenkau, Dzmitry and Dong, Minjie and
                      Huang, Danni and Wiegand, Simone},
      title        = {{M}olar mass and temperature dependence of the
                      thermodiffusion of polyethylene oxide in water/ethanol
                      mixtures},
      journal      = {The journal of chemical physics},
      volume       = {141},
      number       = {6},
      issn         = {1089-7690},
      address      = {Melville, NY},
      publisher    = {American Institute of Physics},
      reportid     = {FZJ-2014-04389},
      pages        = {064904},
      year         = {2014},
      abstract     = {In this work we study the molar mass dependence of the
                      thermodiffusion of polyethylene oxide at different
                      temperatures in ethanol, water/ethanol mixture
                      $(c_water=0.7)$ and water in a molar mass range up to
                      $M_w=180000$ g/mol. Due to the low solubility of
                      polyethylene oxide oligomers in ethanol the measurements are
                      limited up to $M_w=2200$ g/mol. The specific water/ethanol
                      concentration 0.7 has been chosen, because at this weight
                      fraction the thermal diffusion coefficient, $D_T,$ of
                      water/ethanol vanishes so that the system can be treated as
                      a pseudo binary mixture. The addition of ethanol will
                      degrade the solvent quality, so that we expect a change of
                      the interaction energies between polymer and solvent. The
                      analysis of the experimental data within a theoretical model
                      shows the need of a refined model, which takes specific
                      interactions into account.},
      cin          = {ICS-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ICS-3-20110106},
      pnm          = {451 - Soft Matter Composites (POF2-451)},
      pid          = {G:(DE-HGF)POF2-451},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000340713700054},
      doi          = {10.1063/1.4891720},
      url          = {https://juser.fz-juelich.de/record/155214},
}