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| 001 | 155214 | ||
| 005 | 20240619083500.0 | ||
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| 037 | _ | _ | |a FZJ-2014-04389 |
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| 100 | 1 | _ | |a Wang, Zilin |0 P:(DE-Juel1)144087 |b 0 |u fzj |
| 245 | _ | _ | |a Molar mass and temperature dependence of the thermodiffusion of polyethylene oxide in water/ethanol mixtures |
| 260 | _ | _ | |a Melville, NY |c 2014 |b American Institute of Physics |
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| 520 | _ | _ | |a In this work we study the molar mass dependence of the thermodiffusion of polyethylene oxide at different temperatures in ethanol, water/ethanol mixture (c_water=0.7) and water in a molar mass range up to M_w=180000 g/mol. Due to the low solubility of polyethylene oxide oligomers in ethanol the measurements are limited up to M_w=2200 g/mol. The specific water/ethanol concentration 0.7 has been chosen, because at this weight fraction the thermal diffusion coefficient, D_T, of water/ethanol vanishes so that the system can be treated as a pseudo binary mixture. The addition of ethanol will degrade the solvent quality, so that we expect a change of the interaction energies between polymer and solvent. The analysis of the experimental data within a theoretical model shows the need of a refined model, which takes specific interactions into account. |
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| 700 | 1 | _ | |a Wiegand, Simone |0 P:(DE-Juel1)131034 |b 4 |e Corresponding Author |u fzj |
| 773 | _ | _ | |a 10.1063/1.4891720 |g Vol. 141, no. 6, p. 064904 - |0 PERI:(DE-600)1473050-9 |n 6 |p 064904 |t The @journal of chemical physics |v 141 |y 2014 |x 1089-7690 |
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