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@ARTICLE{Fahey:155462,
author = {Fahey, D. W. F. and Gao, R. S. G. and Möhler, O. M. and
Saathoff, H. S. and Schiller, C. and Ebert, V. E. and
Krämer, Martina and Peter, T. P. and Amarouche, N. A. and
Avallone, L. M. A. and Bauer, Reimar and Bozóki, Z. B. and
Christensen, L. E. C. and Davis, S. M. D. and Durry, G. D.
and Dyroff, C. D. and Herman, R. L. H. and Hunsmann, S. H.
and Khaykin, S. K. and Mackrodt, P. M. and Meyer, J. M. and
Smith, J. B. S. and Spelten, Nicole and Troy, R. F. T. and
Vömel, H. V. and Wagner, S. W. and Wienhold, F. G. W.},
title = {{T}he {A}qua{VIT}-1 {I}ntercomparison of {A}tmosheric
{W}ater {V}apor {M}easurements {T}echniques},
journal = {Atmospheric measurement techniques discussions},
volume = {7},
issn = {1867-8610},
address = {Katlenburg-Lindau},
publisher = {Copernicus},
reportid = {FZJ-2014-04628},
pages = {3159-3251},
year = {2014},
abstract = {The AquaVIT-1 Intercomparison of Atmospheric Water Vapor
Measurement Techniques was conducted at the aerosol and
cloud simulation chamber AIDA at the Karlsruhe Institute of
Technology, Germany, in October 2007. The overall objective
was to intercompare state-of-the-art and prototype
atmospheric hygrometers with each other and with independent
humidity standards under controlled conditions. This
activity was conducted as a blind intercomparison with
coordination by selected referees. The effort was motivated
by persistent discrepancies found in atmospheric
measurements involving multiple instruments operating on
research aircraft and balloon platforms, particularly in the
upper troposphere and lower stratosphere where water vapor
reaches its lowest atmospheric values (less than 10 ppm).
With the AIDA chamber volume of 84 m3, multiple instruments
analyzed air with a common water vapor mixing ratio, either
by extracting air into instrument flow systems, locating
instruments inside the chamber, or sampling the chamber
volume optically. The intercomparison was successfully
conducted over 10 days during which pressure, temperature,
and mixing ratio were systematically varied (50 to 500 hPa,
185 to 243 K, and 0.3 to 152 ppm). In the absence of an
accepted reference instrument, the reference value was taken
to be the ensemble mean of a core subset of the
measurements. For these core instruments, the agreement
between 10 and 150 ppm of water vapor is considered good
with variation about the reference value of about $±10\%$
(±1σ). In the region of most interest between 1 and 10
ppm, the core subset agreement is fair with variation about
the reference value of $±20\%$ (±1σ). The upper limit of
precision was also derived for each instrument from the
reported data. These results indicate that the core
instruments, in general, have intrinsic skill to determine
unknown water vapor mixing ratios with an accuracy of at
least $±20\%.$ The implication for atmospheric measurements
is that the substantially larger differences observed during
in-flight intercomparisons stem from other factors
associated with the moving platforms or the non-laboratory
environment. The success of AquaVIT-1 provides a template
for future intercomparison efforts with water vapor or other
species that are focused on improving the analytical quality
of atmospheric measurements on moving platforms.},
cin = {IEK-7},
ddc = {550},
cid = {I:(DE-Juel1)IEK-7-20101013},
pnm = {234 - Composition and Dynamics of the Upper Troposphere and
Stratosphere (POF2-234)},
pid = {G:(DE-HGF)POF2-234},
typ = {PUB:(DE-HGF)16},
url = {https://juser.fz-juelich.de/record/155462},
}