TY - JOUR AU - Chang, L. J. AU - Schweika, W. AU - Kao, Y.-J. AU - Chou, Y. Z. AU - Perßon, J. AU - Brückel, T. AU - Yang, H. C. AU - Chen, Y. Y. AU - Gardner, J. S. TI - Magnetic correlations in HoxTb2-xTi2O7 JO - Physical review / B VL - 83 IS - 14 SN - 1098-0121 CY - College Park, Md. PB - APS M1 - PreJuSER-15570 SP - 144413 PY - 2011 N1 - This work was supported in Taiwan by Grants No. NSC 96-2739-M-213-001, No. NSC 99-2112-M-007-020 (LJC), No. NSC 97-2628-M-002-011-MY3, and No. NTU 98R0066-65, -68 (Y.Z.C. and Y.J.K.). AB - Polycrystalline samples of HoxTb2-xTi2O7 (0 < x < 2) have been prepared and characterized for their structural and magnetic properties. The parent compounds of this solid solution are the spin ice Ho2Ti2O7 and the spin liquid Tb2Ti2O7. Specific-heat measurements on HoTbTi2O7 (x = 1.0) reveal the absence of a long-range order state above 0.5 K. The integrated entropies of all HoxTb2-xTi2O7 specimens up to 30 K scale well with the ratio of spin ice and spin liquid in the composition. The neutron diffraction spectrum of HoTbTi2O7 exhibits a dipolar spin-ice pattern and can be well described by mean-field theory for < 111 > Ising spins, nearest-neighbor exchange, and dipolar interactions. Inelastic neutron scattering on HoTbTi2O7 reveals two dispersionless excitations, one of similar to 2.5 meV out of the ground state, and a 4-meV transition out of an excited state. We argue that these data suggest that the very strong single-ion effects of Ho2Ti2O7 and Tb2Ti2O7 persist in the HoxTb2-xTi2O7(0 < x < 2) solid solution, whereas the Tb-Ho correlations are weak, resulting in small shifts in the energy scales but with no dramatic effect on the bulk properties. KW - J (WoSType) LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000291973500004 DO - DOI:10.1103/PhysRevB.83.144413 UR - https://juser.fz-juelich.de/record/15570 ER -