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@ARTICLE{Hermus:156410,
author = {Hermus, M. and Yang, M. and Grüner, Daniel and DiSalvo, F.
J. and Fokwa, B. P. T.},
title = {{D}rastic {C}hange of {M}agnetic {I}nteractions and
{H}ysteresis {T}hrough {S}ite-{P}referential {R}u/{I}r
{S}ubstitution in
{S}c$_{2}${F}e{R}u$_{5-x}${I}r$_{x}${B}$_{2}$},
journal = {Chemistry of materials},
volume = {26},
number = {5},
issn = {0897-4756},
address = {Washington, DC},
publisher = {American Chemical Society},
reportid = {FZJ-2014-05153},
pages = {1967-1974},
year = {2014},
abstract = {The quinary members of the complex boride series
Sc2FeRu5–xIrxB2 were synthesized by arc melting the
elements and characterized by powder and single-crystal
X-ray diffraction as well as metallographic and
energy-dispersive X-ray analyses. The use of a 4d/5d mixture
allows distinguishing these elements with X-ray diffraction
methods, thus enabling the study of site preference and its
influence on the magnetic properties.The magnetic
measurements reveal several changes of magnetic ordering
within the series: from antiferromagnetism (Sc2FeRu5B2) to
ferromagnetism (Sc2FeRuIr4B2) and finally to metamagnetism
(Sc2FeIr5B2). Within the quinary series, the magnetic
moments continuously increase with increasing amounts of Ir
in one (8j) of two possible Wyckoff sites. The members with
x = 2 and 3 represent the first hard magnetic borides of
transition metals.},
cin = {IEK-2 / IEF-2},
ddc = {540},
cid = {I:(DE-Juel1)IEK-2-20101013 / I:(DE-Juel1)VDB810},
pnm = {122 - Power Plants (POF2-122)},
pid = {G:(DE-HGF)POF2-122},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000332913400027},
doi = {10.1021/cm500237h},
url = {https://juser.fz-juelich.de/record/156410},
}