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@ARTICLE{Rincn:156425,
      author       = {Rincón, Rosalba A. and Ventosa, Edgar and Tietz, Frank and
                      Masa, Justus and Seisel, Sabine and Kuznetsov, Volodymyr and
                      Schuhmann, Wolfgang},
      title        = {{E}valuation of {P}erovskites as {E}lectrocatalysts for the
                      {O}xygen {E}volution {R}eaction},
      journal      = {ChemPhysChem},
      volume       = {15},
      number       = {13},
      issn         = {1439-4235},
      address      = {Weinheim},
      publisher    = {Wiley-VCH Verl.},
      reportid     = {FZJ-2014-05168},
      pages        = {2810 - 2816},
      year         = {2014},
      abstract     = {The oxygen evolution reaction (OER) is an enabling process
                      for technologies in the area of energy conversion and
                      storage, but its slow kinetics limits its efficiency. We
                      performed an electrochemical evaluation of 14 different
                      perovskites of variable composition and stoichiometry as OER
                      electrocatalysts in alkaline media. We particularly focused
                      on improved methods for a reliable comparison of catalyst
                      activity. From initial electrochemical results we selected
                      the most active samples for further optimization of
                      electrode preparation and testing. An inverted cell
                      configuration facilitated gas bubble detachment and thus
                      minimized blockage of the active surface area. We describe
                      parameters, such as the presence of specific cations,
                      stoichiometry, and conductivity, that are important for
                      obtaining electroactive perovskites for OER. Conductive
                      additives enhanced the current and decreased the apparent
                      overpotential of OER for one of the most active samples
                      (La0.58Sr0.4Fe0.8Co0.2O3).},
      cin          = {IEK-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {123 - Fuel Cells (POF2-123)},
      pid          = {G:(DE-HGF)POF2-123},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000341565600024},
      pubmed       = {pmid:25044985},
      doi          = {10.1002/cphc.201402137},
      url          = {https://juser.fz-juelich.de/record/156425},
}