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@ARTICLE{Wang:15733,
author = {Wang, C.H. and Baker, S.N. and Lumsden, M.D. and Nagler,
S.E. and Heller, W.T. and Baker, G.A. and Deen, P.D. and
Cranswick, L.M.D. and Su, Y. and Christianson, A.D.},
title = {{A}ntiferromagnetic {O}rder in {M}n{O} {S}pherical
{N}anoparticles},
journal = {Physical review / B},
volume = {83},
number = {21},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-15733},
pages = {214418},
year = {2011},
note = {We acknowledge useful discussions with J. Musfeldt and I.
Swainson. Research Work at ORNL was sponsored by the
Laboratory Directed Research and Development Program of
ORNL, and was supported by the Scientific User Facilities
Division Office of Basic Energy Sciences, DOE. A portion of
this research was conducted at the Center for Nanophase
Materials Sciences, which is sponsored at ORNL by the Office
of Basic Energy Sciences, US DOE.},
abstract = {We have performed unpolarized and polarized neutron
diffraction experiments on monodisperse 8- and 13-nm
antiferromagnetic MnO nanoparticles. For the 8-nm sample,
the antiferromagnetic transition temperature T-N (114 K) is
suppressed compared to that in the bulk material (119 K),
while for the 13-nm sample T-N (120 K) is comparable to that
in the bulk. The neutron diffraction data of the
nanoparticles is well described using the bulk MnO magnetic
structure but with a substantially reduced average magnetic
moment of 4.2 +/- 0.3 mu(B)/Mn for the 8-nm sample and 3.9
+/- 0.2 mu(B)/Mn for the 13-nm sample. An analysis of the
polarized neutron data on both samples shows that in an
individual MnO nanoparticle about $80\%$ of Mn ions order.
These results can be explained by a structure in which the
monodisperse nanoparticles studied here have a core that
behaves similar to the bulk with a surface layer which does
not contribute significantly to the magnetic order.},
keywords = {J (WoSType)},
cin = {PGI-4 / JCNS (München) ; Jülich Centre for Neutron
Science JCNS (München) ; JCNS-FRM-II / JCNS-2},
ddc = {530},
cid = {I:(DE-Juel1)PGI-4-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-2-20110106},
pnm = {Grundlagen für zukünftige Informationstechnologien /
Großgeräte für die Forschung mit Photonen, Neutronen und
Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK412 / G:(DE-Juel1)FUEK415},
experiment = {EXP:(DE-MLZ)DNS-20140101},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000291652300002},
doi = {10.1103/PhysRevB.83.214418},
url = {https://juser.fz-juelich.de/record/15733},
}