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@ARTICLE{Abade:15746,
author = {Abade, G.C. and Cichocki, B. and Ekiel-Jezewska, M.L. and
Nägele, G. and Wajnryb, E.},
title = {{R}otational and translational self-diffusion in
concentrated suspensions of permeable particles},
journal = {The journal of chemical physics},
volume = {134},
issn = {0021-9606},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {PreJuSER-15746},
pages = {244903},
year = {2011},
note = {M.L.E-J. and E. W. were supported in part by the Polish
Ministry of Science and Higher Education Grant No. N501
156538. G.N. thanks M. Heinen for helpful discussions and
the Deutsche Forschungsgemeinschaft (SFB-TR6, project B2)
for financial support. Numerical simulations were done at
NACAD-COPPE/UFRJ in Rio de Janeiro, Brazil, and at the
Academic Computer Center in Gdansk, Poland.},
abstract = {In our recent work on concentrated suspensions of uniformly
porous colloidal spheres with excluded volume interactions,
a variety of short-time dynamic properties were calculated,
except for the rotational self-diffusion coefficient. This
missing quantity is included in the present paper. Using a
precise hydrodynamic force multipole simulation method, the
rotational self-diffusion coefficient is evaluated for
concentrated suspensions of permeable particles. Results are
presented for particle volume fractions up to $45\%$ and for
a wide range of permeability values. From the simulation
results and earlier results for the first-order virial
coefficient, we find that the rotational self-diffusion
coefficient of permeable spheres can be scaled to the
corresponding coefficient of impermeable particles of the
same size. We also show that a similar scaling applies to
the translational self-diffusion coefficient considered
earlier. From the scaling relations, accurate analytic
approximations for the rotational and translational
self-diffusion coefficients in concentrated systems are
obtained, useful to the experimental analysis of
permeable-particle diffusion. The simulation results for
rotational diffusion of permeable particles are used to show
that a generalized Stokes-Einstein-Debye relation between
rotational self-diffusion coefficient and high-frequency
viscosity is not satisfied.},
keywords = {J (WoSType)},
cin = {ICS-3},
ddc = {540},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung},
pid = {G:(DE-Juel1)FUEK505},
shelfmark = {Physics, Atomic, Molecular $\&$ Chemical},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:21721660},
UT = {WOS:000292331900058},
doi = {10.1063/1.3604813},
url = {https://juser.fz-juelich.de/record/15746},
}