% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Vereecken:15982,
      author       = {Vereecken, H. and Vanderborght, J. and Kasteel, R. and
                      Spiteller, M. and Schaffer, A. and Close, M.},
      title        = {{D}o {L}ab-{D}erived {D}istribution {C}oefficient {V}alues
                      of {P}esticides {M}atch {D}istribution {C}oefficient
                      {V}alues {D}etermined from {C}olumn and {F}ield-{S}cale
                      {E}xperiments? {A} {C}ritical {A}nalysis of {R}elevant
                      {L}iterature},
      journal      = {Journal of environmental quality},
      volume       = {40},
      issn         = {0047-2425},
      address      = {Madison, Wis.},
      publisher    = {ASA [u.a.]},
      reportid     = {PreJuSER-15982},
      pages        = {879 - 898},
      year         = {2011},
      note         = {Record converted from VDB: 12.11.2012},
      abstract     = {In this study, we analyzed sorption parameters for
                      pesticides that were derived from batch and column or batch
                      and field experiments. The batch experiments analyzed in
                      this study were run with the same pesticide and soil as in
                      the column and field experiments. We analyzed the
                      relationship between the pore water velocity of the column
                      and field experiments, solute residence times, and sorption
                      parameters, such as the organic carbon normalized
                      distribution coefficient ( ) and the mass exchange
                      coefficient in kinetic models, as well as the predictability
                      of sorption parameters from basic soil properties. The
                      batch/column analysis included 38 studies with a total of
                      139 observations. The batch/field analysis included five
                      studies, resulting in a dataset of 24 observations. For the
                      batch/column data, power law relationships between pore
                      water velocity, residence time, and sorption constants were
                      derived. The unexplained variability in these equations was
                      reduced, taking into account the saturation status and the
                      packing status (disturbed-undisturbed) of the soil sample. A
                      new regression equation was derived that allows estimating
                      the values derived from column experiments using organic
                      matter and bulk density with an value of 0.56. Regression
                      analysis of the batch/column data showed that the
                      relationship between batch- and column-derived values
                      depends on the saturation status and packing of the soil
                      column. Analysis of the batch/field data showed that as the
                      batch-derived value becomes larger, field-derived values
                      tend to be lower than the corresponding batch-derived
                      values, and vice versa. The present dataset also showed that
                      the variability in the ratio of batch- to column-derived
                      value increases with increasing pore water velocity, with a
                      maximum value approaching 3.5.},
      keywords     = {Adsorption / Data Interpretation, Statistical /
                      Environmental Monitoring / Geologic Sediments: analysis /
                      Kinetics / Pesticides: analysis / Regression Analysis /
                      Soil: analysis / Soil Pollutants: analysis / Water
                      Pollutants: analysis / Pesticides (NLM Chemicals) / Soil
                      (NLM Chemicals) / Soil Pollutants (NLM Chemicals) / Water
                      Pollutants (NLM Chemicals) / J (WoSType)},
      cin          = {IBG-3},
      ddc          = {333.7},
      cid          = {I:(DE-Juel1)IBG-3-20101118},
      pnm          = {Terrestrische Umwelt},
      pid          = {G:(DE-Juel1)FUEK407},
      shelfmark    = {Environmental Sciences},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:21546674},
      UT           = {WOS:000289886000022},
      doi          = {10.2134/jeq2010.0404},
      url          = {https://juser.fz-juelich.de/record/15982},
}