% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Busse:16070, author = {Busse, C. and Lazic, P. and Djemour, R. and Coraux, J. and Gerber, T. and Atodiresei, N. and Caciuc, V. and Brako, R. and N'Diaye, A.T. and Blügel, S. and Zegenhagen, J. and Michely, T.}, title = {{G}raphene on {I}r(111): {P}hysisorption with {C}hemical {M}odulation}, journal = {Physical review letters}, volume = {107}, issn = {0031-9007}, address = {College Park, Md.}, publisher = {APS}, reportid = {PreJuSER-16070}, pages = {036101}, year = {2011}, note = {P.L. thanks the AvH foundation for support. Financial support of the DFG (Forschergruppe 912, Bu2197/2-1, Mi581/17-2) is gratefully acknowledged. The computations were performed on JUROPA and JUGENE supercomputers at the Julich Supercomputing Center, Forschungszentrum Julich (Germany). The authors thank the staff at ESRF for technical assistance.}, abstract = {The nonlocal van der Waals density functional approach is applied to calculate the binding of graphene to Ir(111). The precise agreement of the calculated mean height (h) over bar = 3.41 angstrom of the C atoms with their mean height (h) over bar = (3.38 +/- 0.04) angstrom as measured by the x-ray standing wave technique provides a benchmark for the applicability of the nonlocal functional. We find bonding of graphene to Ir(111) to be due to the van der Waals interaction with an antibonding average contribution from chemical interaction. Despite its globally repulsive character, in certain areas of the large graphene moire unit cell charge accumulation between Ir substrate and graphene C atoms is observed, signaling a weak covalent bond formation.}, keywords = {J (WoSType)}, cin = {PGI-1 / IAS-1}, ddc = {550}, cid = {I:(DE-Juel1)PGI-1-20110106 / I:(DE-Juel1)IAS-1-20090406}, pnm = {Grundlagen für zukünftige Informationstechnologien}, pid = {G:(DE-Juel1)FUEK412}, shelfmark = {Physics, Multidisciplinary}, typ = {PUB:(DE-HGF)16}, UT = {WOS:000292690400004}, doi = {10.1103/PhysRevLett.107.036101}, url = {https://juser.fz-juelich.de/record/16070}, }