001     16355
005     20200702121602.0
024 7 _ |2 pmid
|a pmid:21678900
024 7 _ |2 DOI
|a 10.1021/es1036578
024 7 _ |2 WOS
|a WOS:000292850200022
024 7 _ |2 ISSN
|a 0013-936X
024 7 _ |2 ISSN
|a 1520-5851
037 _ _ |a PreJuSER-16355
041 _ _ |a eng
082 _ _ |a 050
084 _ _ |2 WoS
|a Engineering, Environmental
084 _ _ |2 WoS
|a Environmental Sciences
100 1 _ |0 P:(DE-HGF)0
|a Wang, R.
|b 0
245 _ _ |a Measurement of N2, N2O, NO and CO2 emissions from soil with the gas-flow-soil-core technique
260 _ _ |a Columbus, Ohio
|b American Chemical Society
|c 2011
300 _ _ |a 6066 - 6072
336 7 _ |a Journal Article
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336 7 _ |a article
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440 _ 0 |0 1865
|a Environmental Science and Technology
|v 45
|x 0013-936X
|y 14
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a This work was funded by the German Research Foundation (DFG, FG536, MAGIM), the National Natural Science Foundation of China (40805061, 41021004), and the NitroEurope project. Technical assistance from Meike Sauerwein, Guangren Liu, Yinghong Wang, Yang Sun, and Dongsheng Ji is acknowledged.
520 _ _ |a Here we describe a newly designed system with three stand-alone working incubation vessels for simultaneous measurements of N(2), N(2)O, NO, and CO(2) emissions from soil. Due to the use of a new micro thermal conductivity detector and the redesign of vessels and gas sampling a so-far unmatched sensitivity (0.23 μg N(2)-N h(-1) kg(-1) ds or 8.1 μg N(2)-N m(-2) h(-1)) for detecting N(2) gas emissions and repeatability of experiments could be achieved. We further tested different incubation methods to improve the quantification of N(2) emission via denitrification following the initialization of soil anaerobiosis. The best results with regard to the establishment of a full N balance (i.e., the changes in mineral N content being offset by simultaneous emission of N gases) were obtained when the anaerobic soil incubation at 25 °C was preceded by soil gas exchange under aerobic conditions at a lower incubation temperature. The ratios of N and C gas emission changed very dynamically following the initialization of anaerobiosis. For soil NO(3)(-) contents of 50 mg N kg(-1) dry soil (ds) and dissolved organic carbon (DOC) concentrations of approximately 300 mg C kg(-1) ds, the cumulative emissions of N(2), N(2)O, and NO were 24.3 ± 0.1, 12.6 ± 0.4, and 10.1 ± 0.3 mg N kg(-1) ds, respectively. Thus, N gas emissions accounted (on average) for 46.2% (N(2)), 24.0% (N(2)O), and 19.2% (NO) of the observed changes in soil NO(3)(-). The maximum N(2) emission reached 1200 μg N h(-1) kg(-1) ds, whereas the peak emissions of N(2)O and NO were lower by a factor of 2-3. The overall N(2):N(2)O and NO:N(2)O molar ratios were 1.6-10.0 and 1.6-2.3, respectively. The measurement system provides a reliable tool for studying denitrification in soil because it offers insights into the dynamics and magnitude of gaseous N emissions due to denitrification under various incubation conditions.
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588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Anaerobiosis
650 _ 2 |2 MeSH
|a Atmosphere: chemistry
650 _ 2 |2 MeSH
|a Carbon Dioxide: analysis
650 _ 2 |2 MeSH
|a Chemistry Techniques, Analytical
650 _ 2 |2 MeSH
|a Models, Chemical
650 _ 2 |2 MeSH
|a Nitrogen: analysis
650 _ 2 |2 MeSH
|a Nitrogen Oxides: analysis
650 _ 2 |2 MeSH
|a Soil: chemistry
650 _ 7 |0 0
|2 NLM Chemicals
|a Nitrogen Oxides
650 _ 7 |0 0
|2 NLM Chemicals
|a Soil
650 _ 7 |0 124-38-9
|2 NLM Chemicals
|a Carbon Dioxide
650 _ 7 |0 7727-37-9
|2 NLM Chemicals
|a Nitrogen
650 _ 7 |2 WoSType
|a J
700 1 _ |0 P:(DE-HGF)0
|a Willibald, G.
|b 1
700 1 _ |0 P:(DE-HGF)0
|a Feng, Q.
|b 2
700 1 _ |0 P:(DE-HGF)0
|a Zheng, X.
|b 3
700 1 _ |0 P:(DE-HGF)0
|a Liao, T.
|b 4
700 1 _ |0 P:(DE-Juel1)142357
|a Brüggemann, N.
|b 5
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Butterbach-Bahl, K.
|b 6
773 _ _ |0 PERI:(DE-600)1465132-4
|a 10.1021/es1036578
|g Vol. 45, p. 6066 - 6072
|p 6066 - 6072
|q 45<6066 - 6072
|t Environmental Science & Technology
|v 45
|x 0013-936X
|y 2011
856 7 _ |u http://dx.doi.org/10.1021/es1036578
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