000016363 001__ 16363 000016363 005__ 20230426083026.0 000016363 0247_ $$2DOI$$a10.1103/PhysRevB.83.085416 000016363 0247_ $$2WOS$$aWOS:000287485000004 000016363 0247_ $$2Handle$$a2128/10922 000016363 037__ $$aPreJuSER-16363 000016363 041__ $$aeng 000016363 082__ $$a530 000016363 084__ $$2WoS$$aPhysics, Condensed Matter 000016363 1001_ $$0P:(DE-Juel1)VDB93048$$aStadtmüller, B.$$b0$$uFZJ 000016363 245__ $$aSubmonolayer growth of CuPc on noble metal surfaces 000016363 260__ $$aCollege Park, Md.$$bAPS$$c2011 000016363 300__ $$a085416 000016363 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article 000016363 3367_ $$2DataCite$$aOutput Types/Journal article 000016363 3367_ $$00$$2EndNote$$aJournal Article 000016363 3367_ $$2BibTeX$$aARTICLE 000016363 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000016363 3367_ $$2DRIVER$$aarticle 000016363 440_0 $$04919$$aPhysical Review B$$v83$$x1098-0121$$y8 000016363 500__ $$3POF3_Assignment on 2016-02-29 000016363 500__ $$aWe thank A. Scholl, J. Ziroff and M. Haming for stimulating discussions and acknowledge financial support from the Deutsche Forschungsgemeinschaft (Grant No. KU 1531/2-1 and Graduiertenkolleg GK 1221) and the Bundesministerium fur Bildung und Forschung (BMBF Grant No. 03SF0356B GREKOS). 000016363 520__ $$aThe understanding of growth mechanisms and electronic properties is a key issue for improving the performance of small organic devices, in which the metal-organic interface and its properties play a crucial role. In this context we investigated the adsorption behavior and the electronic properties of copper-II-phthalocyanine (CuPc) within the first adsorbate layer on Au(111) and Cu(111). Together with recent results published for CuPc/Ag(111) [Kroger et al., New J. Phys. 12, 083038 (2010)] this leads to a comprehensive understanding of the adsorption of CuPc on noble metal surfaces: On Cu(111) the molecule-surface interaction is the strongest. The molecules chemisorb on the surface and form one-dimensional chains or two-dimensional islands, depending on coverage. This behavior indicates an attractive intermolecular interaction. In contrast, on Au(111) CuPc is only weakly physisorbed and behaves like a two-dimensional gas in a wide coverage regime. Only when densely packed do the molecules form ordered structures, which are scarcely influenced by the structure of the metallic surface. Molecule-molecule interaction is also very weak, but in contrast to CuPc on Ag(111) no clear indications for a repulsive interaction are found. Regarding the adsorption strength, this latter system represents an (possibly unique) intermediate case which enables the unusual intermolecular repulsion found recently. Our results highlight the special role of this model system, since the interaction of CuPc with the metal can be "tuned" in any order of the adsorption scenarios observed by selecting the right substrate material. 000016363 536__ $$0G:(DE-Juel1)FUEK412$$2G:(DE-HGF)$$aGrundlagen für zukünftige Informationstechnologien$$cP42$$x0 000016363 542__ $$2Crossref$$i2011-02-18$$uhttp://link.aps.org/licenses/aps-default-license 000016363 588__ $$aDataset connected to Web of Science 000016363 650_7 $$2WoSType$$aJ 000016363 7001_ $$0P:(DE-Juel1)VDB93047$$aKröger, I.$$b1$$uFZJ 000016363 7001_ $$0P:(DE-HGF)0$$aReinert, F.$$b2 000016363 7001_ $$0P:(DE-Juel1)VDB77884$$aKumpf, C.$$b3$$uFZJ 000016363 77318 $$2Crossref$$3journal-article$$a10.1103/physrevb.83.085416$$bAmerican Physical Society (APS)$$d2011-02-18$$n8$$p085416$$tPhysical Review B$$v83$$x1098-0121$$y2011 000016363 773__ $$0PERI:(DE-600)2844160-6$$a10.1103/PhysRevB.83.085416$$gVol. 83, p. 085416$$n8$$p085416$$q83<085416$$tPhysical review / B$$v83$$x1098-0121$$y2011 000016363 8567_ $$uhttp://dx.doi.org/10.1103/PhysRevB.83.085416 000016363 8564_ $$uhttps://juser.fz-juelich.de/record/16363/files/PhysRevB.83.085416.pdf$$yOpenAccess 000016363 8564_ $$uhttps://juser.fz-juelich.de/record/16363/files/PhysRevB.83.085416.gif?subformat=icon$$xicon$$yOpenAccess 000016363 8564_ $$uhttps://juser.fz-juelich.de/record/16363/files/PhysRevB.83.085416.jpg?subformat=icon-180$$xicon-180$$yOpenAccess 000016363 8564_ $$uhttps://juser.fz-juelich.de/record/16363/files/PhysRevB.83.085416.jpg?subformat=icon-700$$xicon-700$$yOpenAccess 000016363 8564_ $$uhttps://juser.fz-juelich.de/record/16363/files/PhysRevB.83.085416.pdf?subformat=pdfa$$xpdfa$$yOpenAccess 000016363 909CO $$ooai:juser.fz-juelich.de:16363$$pdnbdelivery$$pVDB$$pdriver$$popen_access$$popenaire 000016363 9141_ $$y2011 000016363 915__ $$0LIC:(DE-HGF)APS-112012$$2HGFVOC$$aAmerican Physical Society Transfer of Copyright Agreement 000016363 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess 000016363 915__ $$0StatID:(DE-HGF)0010$$aJCR/ISI refereed 000016363 9131_ $$0G:(DE-Juel1)FUEK412$$aDE-HGF$$bSchlüsseltechnologien$$kP42$$lGrundlagen für zukünftige Informationstechnologien (FIT)$$vGrundlagen für zukünftige Informationstechnologien$$x0 000016363 9132_ $$0G:(DE-HGF)POF3-529H$$1G:(DE-HGF)POF3-520$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lFuture Information Technology - 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