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| 001 | 16365 | ||
| 005 | 20211110141630.0 | ||
| 024 | 7 | _ | |a 10.1088/1367-2630/12/8/083038 |2 DOI |
| 024 | 7 | _ | |a WOS:000281279700004 |2 WOS |
| 024 | 7 | _ | |a 2128/28967 |2 Handle |
| 037 | _ | _ | |a PreJuSER-16365 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 530 |
| 084 | _ | _ | |2 WoS |a Physics, Multidisciplinary |
| 100 | 1 | _ | |0 P:(DE-Juel1)VDB93047 |a Kröger, I. |b 0 |u FZJ |
| 245 | _ | _ | |a Submonolayer growth of copper-phthalocyanine on Ag(111) |
| 260 | _ | _ | |a [Bad Honnef] |b Dt. Physikalische Ges. |c 2010 |
| 300 | _ | _ | |a 083038 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
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| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |0 8201 |a New Journal of Physics |v 12 |x 1367-2630 |y 8 |
| 500 | _ | _ | |a We acknowledge financial support from the Deutsche Forschungsgemeinschaft (KU 1531/2-1, GK 1221 and FOR 1162) and from the ESRF, Grenoble, France. |
| 520 | _ | _ | |a The growth of high-quality thin films is a key issue in the ability to design electronic devices based on organic materials and to tune their properties. In this context, the interfaces between metals and organic films play a decisive role. Here, we report on the interface formation between copper-phthalocyanine (CuPc) and an Ag(111) surface using various complementary methods. High-resolution low-energy electron diffraction revealed a rich phase diagram for this system with disordered (two-dimensional (2D)-gas-like) and ordered structures (commensurate and point-on-line). In particular, a continuous change in lattice parameters with increasing coverage was found for long-range ordered structures, indicating a substrate-mediated repulsive intermolecular interaction similar to the case of tin-phthalocyanine/Ag(111). Chemisorptivebonding to the substrate was found by x-ray standing waves and ultraviolet photoelectron spectroscopy, and this weakened with increasing coverage at low temperature. This remarkable effect is correlated to a shift in the highest occupied molecular orbital (HOMO) and a HOMO-1 split off band to higher binding energies. Based on our experimental results, we present a comprehensive study of the adsorption behavior of CuPc/Ag(111), including the mechanisms for phase formation and molecular interaction. |
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| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Stadler, C. |b 2 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Ziroff, J. |b 3 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Kochler, M. |b 4 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Stahl, A. |b 5 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Pollinger, F. |b 6 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Lee, T.-L. |b 7 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Zegenhagen, J. |b 8 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Reinert, F. |b 9 |
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| 773 | _ | _ | |0 PERI:(DE-600)1464444-7 |a 10.1088/1367-2630/12/8/083038 |g Vol. 12, p. 083038 |p 083038 |q 12<083038 |t New journal of physics |v 12 |x 1367-2630 |y 2010 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1088/1367-2630/12/8/083038 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/16365/files/Kr%C3%B6ger_2010_New_J._Phys._12_083038.pdf |y OpenAccess |
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