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@ARTICLE{Li:16413,
      author       = {Li, C.L. and Berns, A.E. and Schaffer, A. and Sequaris,
                      J.M. and Vereecken, H. and Ji, R. and Klumpp, E.},
      title        = {{E}ffect of structural composition of humic acids on the
                      sorption of a branched nonylphenol isomer},
      journal      = {Chemosphere},
      volume       = {84},
      issn         = {0045-6535},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {PreJuSER-16413},
      pages        = {409 - 414},
      year         = {2011},
      note         = {Chengliang Li was supported by a scholarship from the
                      Deutscher Akademischer Austausch Dienst (DAAD). This study
                      was financed by the National Natural Science Foundation of
                      China (Project Nos.: 20777033 and 20977043). We thank Mr.
                      Jun Shan and Mr. Xuesen Bian for their kind help in sampling
                      sediments from the Yangtze River.},
      abstract     = {By using dialysis equilibrium experiments, the sorption of
                      a branched nonylphenol isomer
                      [4-(1-ethyl-1,3-dimethylpentyl)-phenol] (NP111) on various
                      humic acids (HAs) isolated from river sediments and two
                      reference HAs was studied. The HAs were characterized by
                      solid-state (13)C direct polarization/magic angle spinning
                      nuclear magnetic resonance ((13)C DP/MAS NMR) spectroscopy.
                      Sorption isotherms of NP111 on HAs were described by a
                      linear model. The organic carbon-normalized sorption
                      coefficient (K(OC)) ranged from 2.3×10(3) to
                      1.5×10(4)Lkg(-1). Interestingly, a clear correlation
                      between K(OC) value and alkyl C content was observed,
                      indicating that the aliphaticity of HAs markedly dominates
                      the sorption of NP111. These new mechanistic insights about
                      the NP111 sorption indicate that the fate of nonylphenols in
                      soil or sediment depends not only on the content of HA, but
                      also on its structural composition.},
      keywords     = {Adsorption / Geologic Sediments: chemistry / Humic
                      Substances / Isomerism / Linear Models / Magnetic Resonance
                      Spectroscopy / Models, Chemical / Molecular Structure /
                      Phenols: chemistry / Water Pollutants, Chemical: chemistry /
                      Humic Substances (NLM Chemicals) / Phenols (NLM Chemicals) /
                      Water Pollutants, Chemical (NLM Chemicals) / nonylphenol
                      (NLM Chemicals) / J (WoSType)},
      cin          = {IBG-3},
      ddc          = {333.7},
      cid          = {I:(DE-Juel1)IBG-3-20101118},
      pnm          = {Terrestrische Umwelt},
      pid          = {G:(DE-Juel1)FUEK407},
      shelfmark    = {Environmental Sciences},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:21524780},
      UT           = {WOS:000292716000007},
      doi          = {10.1016/j.chemosphere.2011.03.057},
      url          = {https://juser.fz-juelich.de/record/16413},
}