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@ARTICLE{Schlipf:16695,
author = {Schlipf, M. and Betzinger, M. and Friedrich, C. and Lezaic,
M. and Blügel, S.},
title = {{HSE} hybrid functional within the {FLAPW} method and its
application to {G}d{N}},
journal = {Physical review / B},
volume = {84},
number = {12},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-16695},
pages = {125142},
year = {2011},
note = {We would like to thank Walter Lambrecht for fruitful
discussions on GdN. We gratefully acknowledge the funding by
the Young Investigators Group Programme of the Helmholtz
Association ("Computational Nanoferronics Laboratory,"
Contract VH-NG-409) and by the Deutsche
Forschungsgemeinschaft through the Priority Program 1145.},
abstract = {We present an implementation of the Heyd-Scuseria-Ernzerhof
(HSE) hybrid functional within the full-potential linearized
augmented-plane-wave (FLAPW) method. Pivotal to the HSE
functional is the screened electron-electron interaction,
which we separate into the bare Coulomb interaction and the
remainder. Both terms give rise to exchange potentials,
which sum up to the screened nonlocal exchange potential of
HSE. We evaluate the former with the help of an auxiliary
basis, defined in such a way that the bare Coulomb matrix
becomes sparse. The latter, which is a slowly varying
function in real space, is computed efficiently in
reciprocal space. This approach is general and can be
applied to a whole class of screened hybrid functionals. We
obtain excellent agreement of band gaps and lattice
constants for prototypical semiconductors and insulators
with electronic-structure calculations using plane-wave or
Gaussian basis sets. We apply the HSE hybrid functional to
examine the ground-state properties of rocksalt GdN, which
have been controversially discussed in literature. Our
results indicate that there is a half-metal to insulator
transition occurring between the theoretically optimized
lattice constant at 0 K and the experimental lattice
constant at room temperature. Overall, we attain good
agreement with experimental data for band transitions,
magnetic moments, and the Curie temperature.},
keywords = {J (WoSType)},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-SIM},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / I:(DE-Juel1)VDB1045},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000295484300004},
doi = {10.1103/PhysRevB.84.125142},
url = {https://juser.fz-juelich.de/record/16695},
}