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000016723 084__ $$2WoS$$aChemistry, Multidisciplinary
000016723 084__ $$2WoS$$aChemistry, Physical
000016723 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000016723 1001_ $$0P:(DE-Juel1)VDB74420$$aLennartz, M.C.$$b0$$uFZJ
000016723 245__ $$aDihydroxy (4-thiomorpholinomethyl) benzoic acids - From molecular asymmetry to diode characteristics
000016723 260__ $$aWashington, DC$$bACS Publ.$$c2011
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000016723 500__ $$aThis work was funded by the DFG (Grant SPP1243). We thank P. Kowalzik for the preparation of the gold samples and A. Besmehn for the execution of the XPS measurements.
000016723 520__ $$aOne of the challenges in molecular electronics is to design molecules which can be used as functional units in electronic devices. The subject of our investigations is an asymmetrical molecule, dihydroxy(4-thiomorpholinomethyl)benzoic acid (TMBA), whose structural and electronic properties are characterized. The self-assembly behavior of TMBA on Au(111) surfaces resulting in highly ordered monolayers is obtained using scanning tunneling microscopy (STM). Furthermore, investigations on the electronic properties of the combined metal/molecule system reveal an orbital mediated tunneling process and tunneling decay constants for the carboxylic and thiomorpholino group. Thus, a diode-like character of TMBA is shown to be caused by intrinsic electronic properties of different molecular moieties.
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000016723 7001_ $$0P:(DE-HGF)0$$aBaumert, M.$$b1
000016723 7001_ $$0P:(DE-Juel1)130751$$aKarthäuser, S.$$b2$$uFZJ
000016723 7001_ $$0P:(DE-HGF)0$$aAlbrecht, M.$$b3
000016723 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b4$$uFZJ
000016723 773__ $$0PERI:(DE-600)2005937-1$$a10.1021/la201206e$$gVol. 27$$q27$$tLangmuir$$v27$$x0743-7463$$y2011
000016723 8567_ $$uhttp://dx.doi.org/10.1021/la201206e
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