Hauptseite > Publikationsdatenbank > Dihydroxy (4-thiomorpholinomethyl) benzoic acids - From molecular asymmetry to diode characteristics > print

001     16723
005     20180208202850.0
024 7 _ |2 pmid
|a pmid:21749130
024 7 _ |2 DOI
|a 10.1021/la201206e
024 7 _ |2 WOS
|a WOS:000293662800082
037 _ _ |a PreJuSER-16723
041 _ _ |a eng
082 _ _ |a 670
084 _ _ |2 WoS
|a Chemistry, Multidisciplinary
084 _ _ |2 WoS
|a Chemistry, Physical
084 _ _ |2 WoS
|a Materials Science, Multidisciplinary
100 1 _ |0 P:(DE-Juel1)VDB74420
|a Lennartz, M.C.
|b 0
|u FZJ
245 _ _ |a Dihydroxy (4-thiomorpholinomethyl) benzoic acids - From molecular asymmetry to diode characteristics
260 _ _ |a Washington, DC
|b ACS Publ.
|c 2011
336 7 _ |a Journal Article
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|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |0 4081
|a Langmuir
|v 27
|x 0743-7463
|y 10312
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a This work was funded by the DFG (Grant SPP1243). We thank P. Kowalzik for the preparation of the gold samples and A. Besmehn for the execution of the XPS measurements.
520 _ _ |a One of the challenges in molecular electronics is to design molecules which can be used as functional units in electronic devices. The subject of our investigations is an asymmetrical molecule, dihydroxy(4-thiomorpholinomethyl)benzoic acid (TMBA), whose structural and electronic properties are characterized. The self-assembly behavior of TMBA on Au(111) surfaces resulting in highly ordered monolayers is obtained using scanning tunneling microscopy (STM). Furthermore, investigations on the electronic properties of the combined metal/molecule system reveal an orbital mediated tunneling process and tunneling decay constants for the carboxylic and thiomorpholino group. Thus, a diode-like character of TMBA is shown to be caused by intrinsic electronic properties of different molecular moieties.
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|a Baumert, M.
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700 1 _ |0 P:(DE-Juel1)130751
|a Karthäuser, S.
|b 2
|u FZJ
700 1 _ |0 P:(DE-HGF)0
|a Albrecht, M.
|b 3
700 1 _ |0 P:(DE-Juel1)131022
|a Waser, R.
|b 4
|u FZJ
773 _ _ |0 PERI:(DE-600)2005937-1
|a 10.1021/la201206e
|g Vol. 27
|q 27
|t Langmuir
|v 27
|x 0743-7463
|y 2011
856 7 _ |u http://dx.doi.org/10.1021/la201206e
909 C O |o oai:juser.fz-juelich.de:16723
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914 1 _ |y 2011
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
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