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@ARTICLE{Gerstl:17151,
author = {Gerstl, C. and Schneider, G.J. and Pyckhout-Hintzen, W. and
Allgaier, J. and Willbold, S. and Hofmann, D. and Disko, U.
and Frielinghaus, H. and Richter, D.},
title = {{C}hain conformation of {P}oly(alkylene oxide)s studied by
{S}mall-{A}ngle {N}eutron {S}cattering},
journal = {Macromolecules},
volume = {44},
issn = {0024-9297},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PreJuSER-17151},
pages = {6077 - 6084},
year = {2011},
note = {We thank Lewis Fetters for his valuable comments. C.G.
acknowledges financial support by the International
Helmholtz Research School of Biophysics and Soft Matter
(IHRS BioSoft).},
abstract = {Using small-angle neutron scattering, the unperturbed chain
dimensions of a series of poly(alkylene oxide)s (PAO's) were
studied as a function of side-chain length. The PAO's were
obtained using anionic ring-opening polymerization methods.
The deuterated monomers were synthesized from commercially
available precomponents. A systematic decrease of the chain
dimensions with increasing length of the side chains was
found. We also compare the PAO's with the chemically very
similar poly(olefin)s with respect to the characteristic
ratio C-infinity, the chain dimensions, and the packing
length as a function of the molecular weight per backbone
bond. In doing so, we found significant differences between
the static properties of the two systems.},
keywords = {J (WoSType)},
cin = {ICS-1 / JCNS-1 / JCNS (München) ; Jülich Centre for
Neutron Science JCNS (München) ; JCNS-FRM-II / ZCH / IBG-3},
ddc = {540},
cid = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-Juel1)ZCH-20090406
/ I:(DE-Juel1)IBG-3-20101118},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / Großgeräte für die Forschung
mit Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
shelfmark = {Polymer Science},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000293353800033},
doi = {10.1021/ma201288a},
url = {https://juser.fz-juelich.de/record/17151},
}