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@ARTICLE{Goossen:171701,
      author       = {Goossen, Sebastian and Bras, Ana and Krutyeva, M. and
                      Sharp, M. and Falus, P. and Feoktystov, A. and Gasser, U.
                      and Pyckhout-Hintzen, W. and Wischnewski, A. and Richter,
                      D.},
      title        = {{M}olecular {S}cale {D}ynamics of {L}arge {R}ing
                      {P}olymers},
      journal      = {Physical review letters},
      volume       = {113},
      number       = {16},
      issn         = {1079-7114},
      address      = {College Park, Md.},
      publisher    = {APS},
      reportid     = {FZJ-2014-05270},
      pages        = {168302},
      year         = {2014},
      abstract     = {We present neutron scattering data on the structure and
                      dynamics of melts from polyethylene oxide rings with
                      molecular weights up to ten times the entanglement mass of
                      the linear counterpart. The data reveal a very compact
                      conformation displaying a structure approaching a mass
                      fractal, as hypothesized by recent simulation work. The
                      dynamics is characterized by a fast Rouse relaxation of
                      subunits (loops) and a slower dynamics displaying a lattice
                      animal-like loop displacement. The loop size is an intrinsic
                      property of the ring architecture and is independent of
                      molecular weight. This is the first experimental observation
                      of the space-time evolution of segmental motion in ring
                      polymers illustrating the dynamic consequences of their
                      topology that is unique among all polymeric systems of any
                      other known architecture.},
      cin          = {ICS-1 / JCNS (München) ; Jülich Centre for Neutron
                      Science JCNS (München) ; JCNS-FRM-II / Neutronenstreuung ;
                      JCNS-1},
      ddc          = {550},
      cid          = {I:(DE-Juel1)ICS-1-20110106 /
                      I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {451 - Soft Matter Composites (POF2-451) / 54G - JCNS
                      (POF2-54G24)},
      pid          = {G:(DE-HGF)POF2-451 / G:(DE-HGF)POF2-54G24},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000344032500011},
      doi          = {10.1103/PhysRevLett.113.168302},
      url          = {https://juser.fz-juelich.de/record/171701},
}