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024 7 _ |a 10.1063/1.4896399
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037 _ _ |a FZJ-2014-05278
082 _ _ |a 530
100 1 _ |a Pradheesh, R.
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245 _ _ |a Magnetization-steps in Y$_{2}$CoMnO$_{6}$ double perovskite: The role of antisite disorder
260 _ _ |a Melville, NY
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|b American Inst. of Physics
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520 _ _ |a Antisite disorder is observed to have significant impact on the magnetic properties of the double perovskite Y2CoMnO6 which has been recently identified as a multiferroic. A paramagnetic-ferromagnetic phase transition occurs in this material at Tc ≈ 75 K. At 2 K, it displays a strong ferromagnetic hysteresis with a significant coercive field of Hc ≈ 15 kOe. Sharp steps are observed in the hysteresis curves recorded below 8 K. In the temperature range 2 K ≤ T ≤ 5 K, the hysteresis loops are anomalous as the virgin curve lies outside the main loop. The field-cooling conditions as well as the rate of field-sweep are found to influence the steps. Quantitative analysis of the neutron diffraction data shows that at room temperature, Y2CoMnO6 consists of 62% of monoclinic P21/n with nearly 70% antisite disorder and 38% Pnma. The bond valence sums indicate the presence of other valence states for Co and Mn which arise from disorder. We explain the origin of steps by using a model for pinning of magnetization at the antiphase boundaries created by antisite disorder. The steps in magnetization closely resemble the martensitic transformations found in intermetallics and display first-order characteristics as revealed in the Arrott's plots.
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700 1 _ |a Cherian, Dona
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700 1 _ |a Elizabeth, Suja
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700 1 _ |a Nair, Harikrishnan
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773 _ _ |a 10.1063/1.4896399
|g Vol. 116, no. 12, p. 123907 -
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