% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Schneider:171845,
      author       = {Schneider, M. and Michels, R. and Pipich, V. and Goerigk,
                      G. and Sauer, V. and Heim, H.-P. and Huber, K.},
      title        = {{M}orphology of {B}lends with {C}ross-{L}inked {PMMA}
                      {M}icrogels and {L}inear {PMMA} {C}hains},
      journal      = {Macromolecules},
      volume       = {46},
      number       = {22},
      issn         = {1520-5835},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2014-05402},
      pages        = {9091 - 9103},
      year         = {2013},
      abstract     = {The present work investigates PMMA colloids in a polymer
                      matrix of linear chains as a simple and suitable system for
                      complex nanocomposites. The investigation was based on SANS
                      experiments, which were enabled by the use of deuterated
                      colloids immersed in a matrix of linear hydrogenated chains.
                      Cross-linked deuterated PMMA-colloids were synthesized with
                      two different sizes (70 and 140 nm) by means of the
                      surfactant-free emulsion polymerization method and the
                      swelling behavior adjusted by varying the amount of added
                      cross-linker (1.5 and 15.0 $mol-\%)$ at each size
                      respectively. Colloid–polymer blends were prepared from
                      colloid–polymer solutions. SANS experiments on these
                      blends consistently revealed that colloids with a low
                      cross-linking density could be homogeneously distributed
                      throughout the matrix of linear chains. Fits with model form
                      factors indicated the structure of fuzzy spheres for these
                      molecularly dispersed microgels, which are slightly swollen
                      with respect to their size and shape in H2O. Contrary to
                      this, colloids with a high cross-linking density form
                      aggregates in the blends. Despite this aggregation, we
                      succeeded to unravel the shape and the size of single
                      colloids by preparation of colloid–polymer blends where
                      the colloid component is a binary mixture of deuterated and
                      hydrogenated colloids both with a high cross-linking
                      density. SANS on the latter blends suggested a core–shell
                      particle in a lattice cell of an aggregate.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {54G - JCNS (POF2-54G24) / 451 - Soft Matter Composites
                      (POF2-451)},
      pid          = {G:(DE-HGF)POF2-54G24 / G:(DE-HGF)POF2-451},
      experiment   = {EXP:(DE-MLZ)KWS3-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000327752900038},
      doi          = {10.1021/ma401889k},
      url          = {https://juser.fz-juelich.de/record/171845},
}