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@ARTICLE{Davaasuren:171849,
author = {Davaasuren, Bambar and Dashjav, Enkhtsetseg and
Rothenberger, Alexander},
title = {{S}ynthesis and {C}haracterization of the {T}ernary
{T}elluroargentate {K} $_{4}$[{A}g $_{18}$ {T}e $_{11}$ ]},
journal = {Zeitschrift für anorganische und allgemeine Chemie},
volume = {640},
number = {14},
issn = {0044-2313},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2014-05406},
pages = {2939-2944},
year = {2014},
abstract = {The ternary potassium telluroargentate(I), K4[Ag18Te11],
was prepared by solvothermal synthesis in ethylenediamine at
160 °C. It crystallizes in the cubic space group Fmequation
imagem (no. 225) with the cell parameter a = 18.6589(6) Å.
The crystal structure can be described as a [Ag18Te11]4–
three-dimensional anionic framework with the voids
accommodating potassium cations. Chemical bonding analysis
reveals polar covalent Ag–Te bonds and considerable
Ag–Ag interactions, which support the complex anionic
character of the structure. The compound is thermally stable
up to 450 °C in an inert atmosphere.},
cin = {IEK-1},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {123 - Fuel Cells (POF2-123)},
pid = {G:(DE-HGF)POF2-123},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000344792300046},
doi = {10.1002/zaac.201400407},
url = {https://juser.fz-juelich.de/record/171849},
}