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@INPROCEEDINGS{Reppert:171892,
author = {Reppert, Thorsten and Tsai, Chih-Long and Lobe, Sandra and
Bünting, Aiko and Finsterbusch, Martin and Dellen,
Christian and Gehrke, Hans-Gregor and Bram, Martin and
Uhlenbruck, Sven and Guillon, Olivier},
title = {{L}i$_{7}${L}a$_{3}${Z}r$_{2}${O}$_{12}$ electrolyte for
all-solid-state batteries},
school = {Ruhr Universität Bochum},
reportid = {FZJ-2014-05448},
year = {2014},
abstract = {A major drawback of conventional Li-ion batteries is the
use of organic liquid electrolytes. As an alternative,
batteries with solid lithium conducting electrolytes are
investigated. One of the promising oxide materials is the
garnet-structured Li7La3Zr2O12 (LLZ) with a competitive
Li-ion conductivity of about 10-4 S/cm. Furthermore, the
material has a good thermal stability (up to 1250°C), is
chemical compatible to metallic lithium, and
electrochemically usable up to 8V vs. Li/Li+. The structural
stability and ion conduction performance can be improved by
partial substitution (e.g. Al, Ta, Y). Furthermore, the
sintering temperature, required to achieve the high
conductive cubic phase, is reduced by doping. An additional
approach is to reduce the thickness of the electrolyte layer
to increase battery performance. At IEK1, we investigate two
main approaches for solid state electrolyte fabrication.
Very thin layers are synthesized by PVD. The aim is to
achieve a thin film battery in the range of a few
micrometers. For large scale fabrication of functional
layers tape casting of LLZ is investigated.},
month = {Oct},
date = {2014-10-17},
organization = {Future Energy Forum 2014, Aachen
(Germany), 17 Oct 2014 - 17 Oct 2014},
cin = {IEK-1},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {435 - Energy Storage (POF2-435) / HITEC - Helmholtz
Interdisciplinary Doctoral Training in Energy and Climate
Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF2-435 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/171892},
}