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| Home > Publications database > Direct Evidence of the Temperature-Induced Molecular Reorientation in Tetracene Thin Films on AlO$_{x}$ /Ni $_{3}$ Al(111)422 > print |
| 001 | 172053 | ||
| 005 | 20210129214350.0 | ||
| 024 | 7 | _ | |2 doi |a 10.1021/jp507773f |
| 024 | 7 | _ | |2 ISSN |a 1932-7447 |
| 024 | 7 | _ | |2 ISSN |a 1932-7455 |
| 024 | 7 | _ | |2 WOS |a WOS:000342652000031 |
| 037 | _ | _ | |a FZJ-2014-05602 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Naboka, Michael |b 0 |
| 245 | _ | _ | |a Direct Evidence of the Temperature-Induced Molecular Reorientation in Tetracene Thin Films on AlO$_{x}$ /Ni $_{3}$ Al(111)422 |
| 260 | _ | _ | |a Washington, DC |b Soc. |c 2014 |
| 336 | 7 | _ | |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |a Journal Article |b journal |m journal |s 1414997941_19702 |
| 336 | 7 | _ | |2 DataCite |a Output Types/Journal article |
| 336 | 7 | _ | |0 0 |2 EndNote |a Journal Article |
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| 336 | 7 | _ | |2 DRIVER |a article |
| 520 | _ | _ | |a Control over the optical properties of the fluorescent organic layer plays a key role in the development of organic light-emitting diodes. A combination of near-edge X-ray absorption fine structure spectroscopy and X-ray photoelectron spectroscopy was used to study structural changes in thin films of tetracene on AlOx/Ni3Al(111). It is shown that upon deposition onto the cold (100 K) substrate, a monolayer of tetracene molecules adopts a disordered adsorption configuration with the molecular planes orientated almost parallel to the surface. Upon annealing at 280 K, the molecular packing changes and the tetracene units adopt a more upright orientation. The consequences of this orientational change for the luminescent properties of the molecular adlayer are discussed, in particular with regard to a quenching of the optical excitation by an electronic coupling of occupied and unoccupied molecular states to those of the metal substrate |
| 536 | _ | _ | |0 G:(DE-HGF)POF2-422 |a 422 - Spin-based and quantum information (POF2-422) |c POF2-422 |f POF II |x 0 |
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| 700 | 1 | _ | |0 P:(DE-Juel1)128790 |a Subach, Sergey |b 1 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Nefedov, Alexei |b 2 |
| 700 | 1 | _ | |0 P:(DE-Juel1)128791 |a Tautz, Frank Stefan |b 3 |u fzj |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Wöll, Christof |b 4 |e Corresponding Author |
| 773 | _ | _ | |0 PERI:(DE-600)2256522-X |a 10.1021/jp507773f |g Vol. 118, no. 39, p. 22678 - 22682 |n 39 |p 22678 - 22682 |t The @journal of physical chemistry |v 118 |x 1932-7455 |y 2014 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/172053/files/FZJ-2014-05602.pdf |y Restricted |
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