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000172189 0247_ $$2ISSN$$a1027-4510
000172189 0247_ $$2ISSN$$a1819-7094
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000172189 037__ $$aFZJ-2014-05686
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000172189 1001_ $$0P:(DE-HGF)0$$aTropin, T. V.$$b0$$eCorresponding Author
000172189 245__ $$aExperimental investigation of C60/NMP/toluene solutions by UV-Vis spectroscopy and small-angle neutron scattering
000172189 260__ $$aMoscow$$bMAIK Nauka/Interperiodics Publ.$$c2013
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000172189 520__ $$aThe transformation of the C60 fullerene cluster state into C60/N-methylpyrrolidone (NMP) solution after the addition of a nonpolar solvent (toluene, electric permittivity ɛ= 2.4) is studied. The results of ultraviolet-visible spectroscopy and small-angle neutron scattering measurements are used for comparison of the C60/NMP/toluene system with C60/NMP mixtures with a high-polar solvent (water, ɛ = 80). As to the observed reorganization of the cluster state, the C60/NMP/toluene system is similar to the C60/NMP/water system. This effect is explained by the formation of charge-transfer complexes in the initial C60/NMP solution. These complexes are thought to be soluble in both binary mixtures. The connection between the cluster-reorganization effect and solvatochromism is discussed.
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000172189 65017 $$0V:(DE-MLZ)GC-140$$2V:(DE-HGF)$$aSoft Matter, Macromolecules, Complex fluids, Biophysics$$x0
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000172189 7001_ $$0P:(DE-HGF)0$$aKyrey, T. O.$$b1
000172189 7001_ $$0P:(DE-HGF)0$$aKyzyma, O. A.$$b2
000172189 7001_ $$0P:(DE-Juel1)144382$$aFeoktystov, Artem$$b3
000172189 7001_ $$0P:(DE-HGF)0$$aAvdeev, M. V.$$b4
000172189 7001_ $$0P:(DE-HGF)0$$aBulavin, L. A.$$b5
000172189 7001_ $$0P:(DE-HGF)0$$aRosta, L.$$b6
000172189 7001_ $$0P:(DE-HGF)0$$aAksenov, V. L.$$b7
000172189 773__ $$0PERI:(DE-600)2389417-9$$a10.1134/S1027451013010199$$gVol. 7, no. 1, p. 1 - 4$$n1$$p1 - 4$$tJournal of surface investigation$$v7$$x1027-4510$$y2013
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