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024 7 _ |2 doi
|a 10.1134/S1027451013010199
024 7 _ |2 ISSN
|a 1027-4510
024 7 _ |2 ISSN
|a 1819-7094
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|a WOS:000315375600001
037 _ _ |a FZJ-2014-05686
082 _ _ |a 530
100 1 _ |0 P:(DE-HGF)0
|a Tropin, T. V.
|b 0
|e Corresponding Author
245 _ _ |a Experimental investigation of C60/NMP/toluene solutions by UV-Vis spectroscopy and small-angle neutron scattering
260 _ _ |a Moscow
|b MAIK Nauka/Interperiodics Publ.
|c 2013
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|s 1429514971_28976
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520 _ _ |a The transformation of the C60 fullerene cluster state into C60/N-methylpyrrolidone (NMP) solution after the addition of a nonpolar solvent (toluene, electric permittivity ɛ= 2.4) is studied. The results of ultraviolet-visible spectroscopy and small-angle neutron scattering measurements are used for comparison of the C60/NMP/toluene system with C60/NMP mixtures with a high-polar solvent (water, ɛ = 80). As to the observed reorganization of the cluster state, the C60/NMP/toluene system is similar to the C60/NMP/water system. This effect is explained by the formation of charge-transfer complexes in the initial C60/NMP solution. These complexes are thought to be soluble in both binary mixtures. The connection between the cluster-reorganization effect and solvatochromism is discussed.
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650 1 7 |a Polymers, Soft Nano Particles and Proteins
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700 1 _ |0 P:(DE-HGF)0
|a Kyrey, T. O.
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|a Kyzyma, O. A.
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700 1 _ |0 P:(DE-Juel1)144382
|a Feoktystov, Artem
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|a Avdeev, M. V.
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700 1 _ |0 P:(DE-HGF)0
|a Bulavin, L. A.
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700 1 _ |0 P:(DE-HGF)0
|a Rosta, L.
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700 1 _ |0 P:(DE-HGF)0
|a Aksenov, V. L.
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773 _ _ |0 PERI:(DE-600)2389417-9
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|g Vol. 7, no. 1, p. 1 - 4
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|t Journal of surface investigation
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|y 2013
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