Home > Publications database > Experimental investigation of C60/NMP/toluene solutions by UV-Vis spectroscopy and small-angle neutron scattering > print |
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024 | 7 | _ | |2 doi |a 10.1134/S1027451013010199 |
024 | 7 | _ | |2 ISSN |a 1027-4510 |
024 | 7 | _ | |2 ISSN |a 1819-7094 |
024 | 7 | _ | |2 WOS |a WOS:000315375600001 |
037 | _ | _ | |a FZJ-2014-05686 |
082 | _ | _ | |a 530 |
100 | 1 | _ | |0 P:(DE-HGF)0 |a Tropin, T. V. |b 0 |e Corresponding Author |
245 | _ | _ | |a Experimental investigation of C60/NMP/toluene solutions by UV-Vis spectroscopy and small-angle neutron scattering |
260 | _ | _ | |a Moscow |b MAIK Nauka/Interperiodics Publ. |c 2013 |
336 | 7 | _ | |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |a Journal Article |b journal |m journal |s 1429514971_28976 |
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520 | _ | _ | |a The transformation of the C60 fullerene cluster state into C60/N-methylpyrrolidone (NMP) solution after the addition of a nonpolar solvent (toluene, electric permittivity ɛ= 2.4) is studied. The results of ultraviolet-visible spectroscopy and small-angle neutron scattering measurements are used for comparison of the C60/NMP/toluene system with C60/NMP mixtures with a high-polar solvent (water, ɛ = 80). As to the observed reorganization of the cluster state, the C60/NMP/toluene system is similar to the C60/NMP/water system. This effect is explained by the formation of charge-transfer complexes in the initial C60/NMP solution. These complexes are thought to be soluble in both binary mixtures. The connection between the cluster-reorganization effect and solvatochromism is discussed. |
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700 | 1 | _ | |0 P:(DE-HGF)0 |a Kyrey, T. O. |b 1 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Kyzyma, O. A. |b 2 |
700 | 1 | _ | |0 P:(DE-Juel1)144382 |a Feoktystov, Artem |b 3 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Avdeev, M. V. |b 4 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Bulavin, L. A. |b 5 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Rosta, L. |b 6 |
700 | 1 | _ | |0 P:(DE-HGF)0 |a Aksenov, V. L. |b 7 |
773 | _ | _ | |0 PERI:(DE-600)2389417-9 |a 10.1134/S1027451013010199 |g Vol. 7, no. 1, p. 1 - 4 |n 1 |p 1 - 4 |t Journal of surface investigation |v 7 |x 1027-4510 |y 2013 |
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