guest ::
| Home > Publications database > Cononsolvency Effects on the Structure and Dynamics of Microgels > print |
| Home > Publications database > Cononsolvency Effects on the Structure and Dynamics of Microgels > print |
| 001 | 172213 | ||
| 005 | 20240619091603.0 | ||
| 024 | 7 | _ | |2 doi |a 10.1021/ma500954t |
| 024 | 7 | _ | |2 ISSN |a 0024-9297 |
| 024 | 7 | _ | |2 ISSN |a 1520-5835 |
| 024 | 7 | _ | |2 WOS |a WOS:000341542900013 |
| 037 | _ | _ | |a FZJ-2014-05702 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |0 P:(DE-Juel1)151337 |a Maccarrone, Simona |b 0 |e Corresponding Author |u fzj |
| 245 | _ | _ | |a Cononsolvency Effects on the Structure and Dynamics of Microgels |
| 260 | _ | _ | |a Washington, DC |b Soc. |c 2014 |
| 336 | 7 | _ | |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |a Journal Article |b journal |m journal |s 1422429505_8061 |
| 336 | 7 | _ | |2 DataCite |a Output Types/Journal article |
| 336 | 7 | _ | |0 0 |2 EndNote |a Journal Article |
| 336 | 7 | _ | |2 BibTeX |a ARTICLE |
| 336 | 7 | _ | |2 ORCID |a JOURNAL_ARTICLE |
| 336 | 7 | _ | |2 DRIVER |a article |
| 520 | _ | _ | |a Sensitive microgels are submicrometer sized, cross-linked polymer particles with a unique swelling behavior changing in response to surrounding conditions like temperature, pH and ionic strength. In this study we influence the swelling capability of thermosensitive microgels microgel by the composition of the solvent (cononsolvency). In particular, we investigate the effects on the structure and dynamics of poly(N-isopropylacrylamide) (PNIPAM) and poly(N,N-diethylacrylamide) (PDEAAM) microgels with different degree of swelling in MeOD/D2O solvent mixture at 10 °C using a combination of small angle neutron scattering (SANS) and neutron spin echo (NSE) spectroscopy at nanoseconds scales in the range of several nanometers. The structural characterization including size and density profiles was determined by fitting SANS data. The dynamical behavior of partially collapsed and swollen microgels is comprehensively described within the theory of semidilute polymers in solutions where hydrodynamic interactions are dominant. The partially collapsed PNIPAM microgel particles are not solid diffusing objects but they have relevant contributions from internal motions. Thus, Zimm segmental dynamics can be detected with elevated apparent viscosity. The swollen PDEAAM microgel particles have a faster internal dynamics compared to the partially collapsed PNIPAM. It can also be explained by Zimm-like relaxations with relatively high apparent viscosity and an additional diffusive contribution coming from the cross-linkers. |
| 536 | _ | _ | |0 G:(DE-HGF)POF2-451 |a 451 - Soft Matter Composites (POF2-451) |c POF2-451 |f POF II |x 0 |
| 536 | _ | _ | |0 G:(DE-HGF)POF2-54G24 |a 54G - JCNS (POF2-54G24) |c POF2-54G24 |f POF II |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, juser.fz-juelich.de |
| 650 | 2 | 7 | |0 V:(DE-MLZ)SciArea-210 |2 V:(DE-HGF) |a Soft Condensed Matter |x 0 |
| 650 | 1 | 7 | |a Polymers, Soft Nano Particles and Proteins |0 V:(DE-MLZ)GC-1602-2016 |2 V:(DE-HGF) |x 2 |
| 650 | 1 | 7 | |a Key Technologies |0 V:(DE-MLZ)GC-150-1 |2 V:(DE-HGF) |x 1 |
| 650 | 1 | 7 | |a Soft Matter, Macromolecules, Complex fluids, Biophysics |0 V:(DE-MLZ)GC-140 |2 V:(DE-HGF) |x 0 |
| 693 | _ | _ | |0 EXP:(DE-MLZ)J-NSE-20140101 |1 EXP:(DE-MLZ)FRMII-20140101 |5 EXP:(DE-MLZ)J-NSE-20140101 |6 EXP:(DE-MLZ)NL2ao-20140101 |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz |e J-NSE: Neutron spin-echo spectrometer |f NL2ao |x 0 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Scherzinger, Christine |b 1 |
| 700 | 1 | _ | |0 P:(DE-Juel1)130718 |a Holderer, Olaf |b 2 |u fzj |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Lindner, Peter |b 3 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Sharp, Melissa |b 4 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Richtering, Walter |b 5 |
| 700 | 1 | _ | |0 P:(DE-Juel1)130917 |a Richter, Dieter |b 6 |u fzj |
| 773 | _ | _ | |0 PERI:(DE-600)1491942-4 |a 10.1021/ma500954t |g Vol. 47, no. 17, p. 5982 - 5988 |n 17 |p 5982 - 5988 |t Macromolecules |v 47 |x 1520-5835 |y 2014 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/172213/files/FZJ-2014-05702.pdf |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:172213 |p VDB:MLZ |p VDB |
| 910 | 1 | _ | |0 I:(DE-588b)5008462-8 |6 P:(DE-Juel1)151337 |a Forschungszentrum Jülich GmbH |b 0 |k FZJ |
| 910 | 1 | _ | |0 I:(DE-588b)5008462-8 |6 P:(DE-Juel1)130718 |a Forschungszentrum Jülich GmbH |b 2 |k FZJ |
| 910 | 1 | _ | |0 I:(DE-588b)5008462-8 |6 P:(DE-Juel1)130917 |a Forschungszentrum Jülich GmbH |b 6 |k FZJ |
| 913 | 2 | _ | |0 G:(DE-HGF)POF3-623 |1 G:(DE-HGF)POF3-620 |2 G:(DE-HGF)POF3-600 |9 G:(DE-HGF)POF3-6G4 |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |v Facility topic: Neutrons for Research on Condensed Matter |x 0 |
| 913 | 2 | _ | |0 G:(DE-HGF)POF3-621 |1 G:(DE-HGF)POF3-620 |2 G:(DE-HGF)POF3-600 |9 G:(DE-HGF)POF3-6215 |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |v In-house research on the structure, dynamics and function of matter |x 1 |
| 913 | 2 | _ | |0 G:(DE-HGF)POF3-600 |1 G:(DE-HGF)POF3 |2 G:(DE-HGF)POF |9 G:(DE-HGF)POF3-6G15 |a DE-HGF |b Programmorientierte Förderung |l POF III |v Forschungsbereich Materie |x 2 |
| 913 | 1 | _ | |0 G:(DE-HGF)POF2-451 |1 G:(DE-HGF)POF2-450 |2 G:(DE-HGF)POF2-400 |a DE-HGF |b Schlüsseltechnologien |v Soft Matter Composites |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF2 |l BioSoft |
| 913 | 1 | _ | |0 G:(DE-HGF)POF2-54G24 |1 G:(DE-HGF)POF2-540 |2 G:(DE-HGF)POF2-500 |a DE-HGF |b Struktur der Materie |v JCNS |x 1 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF2 |l Forschung mit Photonen, Neutronen, Ionen |
| 914 | 1 | _ | |y 2014 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0100 |2 StatID |a JCR |
| 915 | _ | _ | |0 StatID:(DE-HGF)0110 |2 StatID |a WoS |b Science Citation Index |
| 915 | _ | _ | |0 StatID:(DE-HGF)0111 |2 StatID |a WoS |b Science Citation Index Expanded |
| 915 | _ | _ | |0 StatID:(DE-HGF)0150 |2 StatID |a DBCoverage |b Web of Science Core Collection |
| 915 | _ | _ | |0 StatID:(DE-HGF)0199 |2 StatID |a DBCoverage |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |0 StatID:(DE-HGF)0200 |2 StatID |a DBCoverage |b SCOPUS |
| 915 | _ | _ | |0 StatID:(DE-HGF)0300 |2 StatID |a DBCoverage |b Medline |
| 915 | _ | _ | |0 StatID:(DE-HGF)0310 |2 StatID |a DBCoverage |b NCBI Molecular Biology Database |
| 915 | _ | _ | |0 StatID:(DE-HGF)0420 |2 StatID |a Nationallizenz |
| 915 | _ | _ | |0 StatID:(DE-HGF)1150 |2 StatID |a DBCoverage |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |0 StatID:(DE-HGF)9905 |2 StatID |a IF >= 5 |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-1-20110106 |k Neutronenstreuung ; JCNS-1 |l Neutronenstreuung |x 0 |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-FRM-II-20110218 |k JCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II |l JCNS-FRM-II |x 1 |
| 920 | 1 | _ | |0 I:(DE-Juel1)ICS-1-20110106 |k ICS-1 |l Neutronenstreuung |x 2 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-1-20110106 |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-FRM-II-20110218 |
| 980 | _ | _ | |a I:(DE-Juel1)ICS-1-20110106 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IBI-8-20200312 |
| 981 | _ | _ | |a I:(DE-Juel1)JCNS-1-20110106 |
| 981 | _ | _ | |a I:(DE-Juel1)JCNS-FRM-II-20110218 |
| 981 | _ | _ | |a I:(DE-Juel1)ICS-1-20110106 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|