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@ARTICLE{Lathiotakis:172780,
author = {Lathiotakis, Nektarios N. and Helbig, Nicole and Rubio,
Angel and Gidopoulos, Nikitas I.},
title = {{Q}uasi-particle energy spectra in local reduced density
matrix functional theory},
journal = {The journal of chemical physics},
volume = {141},
number = {16},
issn = {0021-9606},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2014-06221},
pages = {164120},
year = {2014},
abstract = {Recently, we introduced [N. N. Lathiotakis, N. Helbig, A.
Rubio, and N. I. Gidopoulos, Phys. Rev. A90, 032511 (2014)]
local reduced density matrix functional theory (local
RDMFT), a theoretical scheme capable of incorporating static
correlation effects in Kohn-Sham equations. Here, we apply
local RDMFT to molecular systems of relatively large size,
as a demonstration of its computational efficiency and its
accuracy in predicting single-electron properties from the
eigenvalue spectrum of the single-particle Hamiltonian with
a local effective potential. We present encouraging results
on the photoelectron spectrum of molecular systems and the
relative stability of C20 isotopes. In addition, we propose
a modelling of the fractional occupancies as functions of
the orbital energies that further improves the efficiency of
the method useful in applications to large systems and
solids.},
cin = {PGI-1 / IAS-1 / JARA-FIT},
ddc = {540},
cid = {I:(DE-Juel1)PGI-1-20110106 / I:(DE-Juel1)IAS-1-20090406 /
$I:(DE-82)080009_20140620$},
pnm = {424 - Exploratory materials and phenomena (POF2-424)},
pid = {G:(DE-HGF)POF2-424},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000344589700022},
pubmed = {pmid:25362285},
doi = {10.1063/1.4899072},
url = {https://juser.fz-juelich.de/record/172780},
}